Fluorescein-formaldehyde oligomeric pH indicator: Facile synthesis, characterization, and potential application
文献类型：期刊论文
| 作者 | Liu, ZH; Gao, SY; Chen, TL |
| 刊名 | JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY
 |
| 出版日期 | 2005-08-01 |
| 卷号 | 43期号:15页码:3447-3453 |
| 关键词 | Characterization Condensation Fluorescein Immobilization Membranes Polymeric Ph Indicator Synthesis |
| ISSN号 | 0887-624X |
| DOI | 10.1002/pola.20850 |
| 英文摘要 | A kind of fluorescent oligomeric pH indicator (fluorescein-formaldehyde product) was synthesized by the reaction of fluorescein with formaldehyde under alkaline conditions by a one-pot method. The synthesized product was fully characterized with Fourier transform infrared, H-1 NMR, ultraviolet-visible spectra, luminescence spectra, and matrix-assisted laser desorption/ionization time-of-flight mass spectra. The results indicated that the reaction was a typical phenol-formaldehyde reaction and that the fluorescein-formaldehyde product contained dimer, trimer, tetramer, and even a little octamer. Visible spectra and luminescence spectra showed that the fluorescein-formaldehyde product could still provide pH sensitivity similar to that of fluorescein. In addition, the oligomeric pH indicator immobilized poly(vinyl alcohol) membranes could be easily fabricated and achieved better long-term stability and fast equilibrium response. Thus, they are promising transparent membranes for optical pH sensors of a wide pH range (0.0-10.0) based on absorption and fluorescence. (c) 2005 Wiley Periodicals, Inc. |
| 语种 | 英语 |
| WOS记录号 | WOS:000230530400024 |
| 出版者 | JOHN WILEY & SONS INC |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/56931]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Chen, TL |
| 作者单位 | 1.Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Polymer Phys & Chem, Changchun 130022, Peoples R China 2.Chinese Acad Sci, Changchun Inst Appl Chem, Sci Res Off, Changchun 130022, Peoples R China |
| 推荐引用方式 GB/T 7714 | Liu, ZH,Gao, SY,Chen, TL. Fluorescein-formaldehyde oligomeric pH indicator: Facile synthesis, characterization, and potential application[J]. JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY,2005,43(15):3447-3453. |
| APA | Liu, ZH,Gao, SY,&Chen, TL.(2005).Fluorescein-formaldehyde oligomeric pH indicator: Facile synthesis, characterization, and potential application.JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY,43(15),3447-3453. |
| MLA | Liu, ZH,et al."Fluorescein-formaldehyde oligomeric pH indicator: Facile synthesis, characterization, and potential application".JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY 43.15(2005):3447-3453. |
入库方式： OAI收割
来源：化学研究所
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