Fabrication of novel conjugated polymer nanostructure: Porphyrins and fullerenes conjugately linked to the polyacetylene backbone as pendant groups
文献类型:期刊论文
| 作者 | Wang, N; Li, YJ; Lu, FS; Liu, Y; He, X; Jiang, L; Zhuang, JP; Li, XF; Li, YL; Wang, S |
| 刊名 | JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY
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| 出版日期 | 2005-07-01 |
| 卷号 | 43期号:13页码:2851-2861 |
| 关键词 | Fullerenes High Performance Polymers Morphology Polyacetylenes Porphyrins |
| ISSN号 | 0887-624X |
| DOI | 10.1002/pola.20757 |
| 英文摘要 | A new series of conjugated polyacetylenes with conjugately linked fullerene and porphyrin groups as pendant units were prepared by a copolymerization reaction catalyzed by chloronorbornadiene rhodium(I)dimer-triethylamine ([Rh(nbd)Cl](2-)NEt3) in anhydrous CHCl3. These polymers were characterized with UV-vis spectroscopy, fluorescence spectroscopy, and voltammetry.. Scanning electron microscopy indicated that the morphology of the copolymers consisted of uniform nanorods with a diameter of about 100 nm and a length of about 300 nm. Thin films of the copolymers produced steady and prompt photocurrent at an irradiation of 20.0 mW cm(-2) of white light, which was higher than that of a mixture of poly[5-(4-Ethynyl-phenyl)10,15,20-tris(4-carbomethoxyphenyl)porphyrin zinc] and C-60. (c) 2005 Wiley Periodicals,Inc. |
| 语种 | 英语 |
| WOS记录号 | WOS:000230014500015 |
| 出版者 | JOHN WILEY & SONS INC |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/57007] ![]() |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Li, YJ |
| 作者单位 | 1.Chinese Acad Sci, Inst Chem, Ctr Mol Sci, Key Lab Organ Solids, Beijing 100080, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100080, Peoples R China 3.Harbin Inst Technol, Dept Appl Phys, Heilongjiang 150001, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wang, N,Li, YJ,Lu, FS,et al. Fabrication of novel conjugated polymer nanostructure: Porphyrins and fullerenes conjugately linked to the polyacetylene backbone as pendant groups[J]. JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY,2005,43(13):2851-2861. |
| APA | Wang, N.,Li, YJ.,Lu, FS.,Liu, Y.,He, X.,...&Zhu, DB.(2005).Fabrication of novel conjugated polymer nanostructure: Porphyrins and fullerenes conjugately linked to the polyacetylene backbone as pendant groups.JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY,43(13),2851-2861. |
| MLA | Wang, N,et al."Fabrication of novel conjugated polymer nanostructure: Porphyrins and fullerenes conjugately linked to the polyacetylene backbone as pendant groups".JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY 43.13(2005):2851-2861. |
入库方式: OAI收割
来源:化学研究所
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