Synthesis, structure characterization, and quantum chemistry of a discrete cluster [{Zn(2,2 '-bipy)(3)}(2)V4O12]center dot 11H(2)O (2,2 '-bipy=2,2 '-bipyridine)
文献类型：期刊论文
| 作者 | Xing, YH; Zhang, YH; Sun, Z; Ge, MF; Yuan, HQ; Zhang, BL |
| 刊名 | SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY
 |
| 出版日期 | 2005 |
| 卷号 | 35期号:10页码:747-753 |
| 关键词 | Synthesis Crystal Structure Oxovanadium Complex Quantum Chemistry |
| ISSN号 | 1553-3174 |
| DOI | 10.1080/15533170500360339 |
| 英文摘要 | A bimetallic cluster complex, [{Zn(2,2'-bipy)(3)}(2)V4O12]center dot 11H(2)O(2,2'-bipy= 2,2'-bipyridine), has been synthesized hydrothermally by a new and more efficient modified way. This complex crystallizes in the monoclinic system with space group C-2/c and cell parameters a = 21.9417(5) angstrom, b = 14.0337(3) angstrom, c = 23.8513(7) angstrom. beta = 106.2(8)degrees and Z = 4 with R-1 = 0.0342. The structure of the complex consists of a discrete anion cluster [V4O12](4-) and the cation {Zn(2,2'-bipy)(3)}(2+) , which is connected by electrostatic force. IR spectra and quantum chemistry data for this complex are given and discussed. |
| 语种 | 英语 |
| WOS记录号 | WOS:000234429400003 |
| 出版者 | TAYLOR & FRANCIS INC |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/57187]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Xing, YH |
| 作者单位 | 1.Liaoning Normal Univ, Bioinorgan Lab, Dalian 116029, Peoples R China 2.Chinese Acad Sci, Inst Chem, Beijing 100080, Peoples R China |
| 推荐引用方式 GB/T 7714 | Xing, YH,Zhang, YH,Sun, Z,et al. Synthesis, structure characterization, and quantum chemistry of a discrete cluster [{Zn(2,2 '-bipy)(3)}(2)V4O12]center dot 11H(2)O (2,2 '-bipy=2,2 '-bipyridine)[J]. SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY,2005,35(10):747-753. |
| APA | Xing, YH,Zhang, YH,Sun, Z,Ge, MF,Yuan, HQ,&Zhang, BL.(2005).Synthesis, structure characterization, and quantum chemistry of a discrete cluster [{Zn(2,2 '-bipy)(3)}(2)V4O12]center dot 11H(2)O (2,2 '-bipy=2,2 '-bipyridine).SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY,35(10),747-753. |
| MLA | Xing, YH,et al."Synthesis, structure characterization, and quantum chemistry of a discrete cluster [{Zn(2,2 '-bipy)(3)}(2)V4O12]center dot 11H(2)O (2,2 '-bipy=2,2 '-bipyridine)".SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY 35.10(2005):747-753. |
入库方式： OAI收割
来源：化学研究所
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