Synthesis, optical, and electrochemical properties of the high-molecular-weight conjugated polycarbazoles
文献类型：期刊论文
| 作者 | Fu, YQ; Bo, ZS |
| 刊名 | MACROMOLECULAR RAPID COMMUNICATIONS
 |
| 出版日期 | 2005-11-01 |
| 卷号 | 26期号:21页码:1704-1710 |
| 关键词 | Chain High Molecular Weight Suzuki Polycondensation Synthesis Poly(2 7-carbazole)s |
| ISSN号 | 1022-1336 |
| DOI | 10.1002/marc.200500478 |
| 英文摘要 | A kind of novel dibromocarbazole monomer hearing three alkyl chains was prepared. Two strategies were developed to improve the solubility molecular weight of carbazole polymers. One was the polymerization of N-octyl-2,7-bis(4,4,5,5-tetramethyl- 1,3,2-dioxaborolan-2-yl)carbazole with the alkylated dibromocarbazole. Another one was the polymerization of N-octyl-2,7-bis(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl.)carbazole with N-octyl-3,6-dibromocarbazole. All the polymerizations were carried Out under palladium-catalyzed Suzuki polycondensation (SPC) conditions. Through using carbazole monomer hearing three alkyl chains to polymerize, we have successfully boosted the number-average molecular weight of 2,7-linked carbazole polymers from not more than 5 to 67 kDa. The high-molecular-weight polymers were obtained in high yields and displayed good solubility in common organic solvents. Their optical, electrochemical, and thermal properties were also reported. |
| 语种 | 英语 |
| WOS记录号 | WOS:000233385600006 |
| 出版者 | WILEY-V C H VERLAG GMBH |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/57191]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Bo, ZS |
| 作者单位 | Chinese Acad Sci, Inst Chem, State Key Lab Polymer Phys & Chem, Beijing 100080, Peoples R China |
| 推荐引用方式 GB/T 7714 | Fu, YQ,Bo, ZS. Synthesis, optical, and electrochemical properties of the high-molecular-weight conjugated polycarbazoles[J]. MACROMOLECULAR RAPID COMMUNICATIONS,2005,26(21):1704-1710. |
| APA | Fu, YQ,&Bo, ZS.(2005).Synthesis, optical, and electrochemical properties of the high-molecular-weight conjugated polycarbazoles.MACROMOLECULAR RAPID COMMUNICATIONS,26(21),1704-1710. |
| MLA | Fu, YQ,et al."Synthesis, optical, and electrochemical properties of the high-molecular-weight conjugated polycarbazoles".MACROMOLECULAR RAPID COMMUNICATIONS 26.21(2005):1704-1710. |
入库方式： OAI收割
来源：化学研究所
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