Supramolecular chirality of the hydrogen-bonded complex Langmuir-Blodgett film of achiral barbituric acid and melamine
文献类型：期刊论文
| 作者 | Huang, X; Li, C; Jiang, SG; Wang, XS; Zhang, BW; Liu, MH |
| 刊名 | JOURNAL OF COLLOID AND INTERFACE SCIENCE
 |
| 出版日期 | 2005-05-15 |
| 卷号 | 285期号:2页码:680-685 |
| 关键词 | Barbituric Acids Circular Dichroism Hydrogen Bonding Lb Film Supramolecular Chirality |
| ISSN号 | 0021-9797 |
| DOI | 10.1016/j.jcis.2004.12.025 |
| 英文摘要 | Complex monolayers of barbituric acid and melamine were formed by spreading a chloroform solution of amphiphilic barbituric acid on the subphase of melamine solution. It was confirmed that the complex monolayer was formed through in situ complementary hydrogen bonding at the air-water interface. It was interesting to find that the complex LB films showed supramolecular chirality although both of the molecules were achiral, as verified by the circular dichroism spectral measurements. It was suggested that the pi-pi stacking of the neighboring barbituric acid and melamine group in a helical sense resulted in the chirality of the molecular assemblies. Due to the directionality of the hydrogen bonding, the BA-M film could form regular aligned nanofibers on the AFM images. Increasing the subphase temperature will lead to the decrease of CD intensity and the change of the morphologies. We suggested that the strength of the hydrogen bonding resulted in the difference. (c) 2005 Elsevier Inc. All rights reserved. |
| 语种 | 英语 |
| WOS记录号 | WOS:000228732900030 |
| 出版者 | ACADEMIC PRESS INC ELSEVIER SCIENCE |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/57229]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Liu, MH |
| 作者单位 | 1.CAS, Inst Chem, CAS Key Lab Colloid & Interface Sci, Beijing 100080, Peoples R China 2.CAS, Tech Inst Phys & Chem, Beijing 100101, Peoples R China |
| 推荐引用方式 GB/T 7714 | Huang, X,Li, C,Jiang, SG,et al. Supramolecular chirality of the hydrogen-bonded complex Langmuir-Blodgett film of achiral barbituric acid and melamine[J]. JOURNAL OF COLLOID AND INTERFACE SCIENCE,2005,285(2):680-685. |
| APA | Huang, X,Li, C,Jiang, SG,Wang, XS,Zhang, BW,&Liu, MH.(2005).Supramolecular chirality of the hydrogen-bonded complex Langmuir-Blodgett film of achiral barbituric acid and melamine.JOURNAL OF COLLOID AND INTERFACE SCIENCE,285(2),680-685. |
| MLA | Huang, X,et al."Supramolecular chirality of the hydrogen-bonded complex Langmuir-Blodgett film of achiral barbituric acid and melamine".JOURNAL OF COLLOID AND INTERFACE SCIENCE 285.2(2005):680-685. |
入库方式： OAI收割
来源：化学研究所
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