Effect of the initial maleic anhydride content on the grafting of maleic anhydride onto isotactic polypropylene
文献类型：期刊论文
| 作者 | Zhang, RH; Zhu, YT; Zhang, JG; Jiang, W; Yin, JH |
| 刊名 | JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY
 |
| 出版日期 | 2005-11-15 |
| 卷号 | 43期号:22页码:5529-5534 |
| 关键词 | Functionalization Of Polymers Grafting Maleic Anhydride Nmr Poly (Propylene) (Pp) |
| ISSN号 | 0887-624X |
| DOI | 10.1002/pola.21038 |
| 英文摘要 | A series of C-13-enriched maleic anhydride grafted isotactic polypropylene samples were prepared in solution at 170 degrees C by changes in the initial maleic anhydride content. The NMR spectra of the samples showed that the signals of the maleic anhydride attached to the tertiary carbons of the isotactic polypropylene chains increased considerably with increasing maleic anhydride content, whereas the signals of the maleic anhydride on the radical chain ends (with a single bond) arising from beta scission did not. On the other hand, the signals of the maleic anhydride on the radical chain ends with double bonds increased markedly with increasing maleic anhydride content, and this suggested that beta scission could occur extensively after maleic anhydride was attached to the tertiary carbons. As a result, the molecular weight of the grafted polypropylene decreased significantly with increasing maleic anhydride content in this study. (c) 2005 Wiley Periodicals, Inc. |
| 语种 | 英语 |
| WOS记录号 | WOS:000232954200015 |
| 出版者 | JOHN WILEY & SONS INC |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/57245]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Zhang, RH |
| 作者单位 | 1.Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Polymer Phys & Chem, Changchun 130022, Peoples R China 2.Chinese Acad Sci, Changchun Inst Appl Chem, Natl Res & Analyt Ctr Electrochem & Spect, Changchun 130022, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhang, RH,Zhu, YT,Zhang, JG,et al. Effect of the initial maleic anhydride content on the grafting of maleic anhydride onto isotactic polypropylene[J]. JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY,2005,43(22):5529-5534. |
| APA | Zhang, RH,Zhu, YT,Zhang, JG,Jiang, W,&Yin, JH.(2005).Effect of the initial maleic anhydride content on the grafting of maleic anhydride onto isotactic polypropylene.JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY,43(22),5529-5534. |
| MLA | Zhang, RH,et al."Effect of the initial maleic anhydride content on the grafting of maleic anhydride onto isotactic polypropylene".JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY 43.22(2005):5529-5534. |
入库方式： OAI收割
来源：化学研究所
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