Fluctuation-assisted crystallization: In a simultaneous phase separation and crystallization polyolefin blend system
文献类型:期刊论文
作者 | Zhang, XH; Wang, ZG; Muthukumar, M; Han, CC |
刊名 | MACROMOLECULAR RAPID COMMUNICATIONS
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出版日期 | 2005-08-19 |
卷号 | 26期号:16页码:1285-1288 |
关键词 | Blends Concentration Fluctuation Crystallization Phase Separation Polyolefins |
ISSN号 | 1022-1336 |
DOI | 10.1002/marc.200500304 |
英文摘要 | The liquid-liquid phase separation (LLPS) is often coupled with other ordering processes such as crystallization. In a polyolefin blend system, overwhelming changes in crystallization kinetics due to concentration fluctuation caused by spontaneous spinodal LLPS have been observed. Consequently, we are proposing a new mechanism of "fluctuation-assisted crystallization". In this process, the usual nucleation barrier could be overcome (or at least partially) by the spontaneous fluctuation growth of LLPS in the spinodal region. |
语种 | 英语 |
WOS记录号 | WOS:000231754300001 |
出版者 | WILEY-V C H VERLAG GMBH |
源URL | [http://ir.iccas.ac.cn/handle/121111/57327] ![]() |
专题 | 中国科学院化学研究所 |
通讯作者 | Han, CC |
作者单位 | 1.Chinese Acad Sci, Inst Chem, State Key Lab Polymer Phys & Chem, Joint Lab Polymer Sci & Mat, Beijing 100080, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100080, Peoples R China 3.Chinese Acad Sci, Inst Chem, CAS Key Lab Engn Plast, Joint Lab Polymer Sci & Mat, Beijing 100080, Peoples R China 4.Univ Massachusetts, Dept Polymer Sci, Amherst, MA 01003 USA |
推荐引用方式 GB/T 7714 | Zhang, XH,Wang, ZG,Muthukumar, M,et al. Fluctuation-assisted crystallization: In a simultaneous phase separation and crystallization polyolefin blend system[J]. MACROMOLECULAR RAPID COMMUNICATIONS,2005,26(16):1285-1288. |
APA | Zhang, XH,Wang, ZG,Muthukumar, M,&Han, CC.(2005).Fluctuation-assisted crystallization: In a simultaneous phase separation and crystallization polyolefin blend system.MACROMOLECULAR RAPID COMMUNICATIONS,26(16),1285-1288. |
MLA | Zhang, XH,et al."Fluctuation-assisted crystallization: In a simultaneous phase separation and crystallization polyolefin blend system".MACROMOLECULAR RAPID COMMUNICATIONS 26.16(2005):1285-1288. |
入库方式: OAI收割
来源:化学研究所
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