Synthesisof C-60-bonded polystyrene initiated with C60Cln/Ni(naph)(2)/P(Ph)(3)
文献类型:期刊论文
作者 | Hua, J; Yang, HQ; Guo, ZX; Xu, L; Chen, DB |
刊名 | JOURNAL OF APPLIED POLYMER SCIENCE
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出版日期 | 2005-11-05 |
卷号 | 98期号:3页码:1215-1218 |
关键词 | Fullerenes Polystyrene Living Polymerization Atrp Optical Property |
ISSN号 | 0021-8995 |
DOI | 10.1002/app.22217 |
英文摘要 | A linear-shaped polystyrene with C-60 core was prepared with a novel initiator system, C60Cln (n average value is 20)/Ni(naph)(2)/P(Ph)(3), and T-p was 130 degrees C. The results of gel-permeation chromatography detected by UV detector and fluorescence spectrum of C-60-PSt demonstrated that C-60 was chemically bonded to polystyrene. The linear increasing of molecular weights (M-n,M-GPC) with conversion indicated that this novel initiator system had some characters of living polymerization. A bathochromic shift was found in the UV-vis spectra curves with increasing concentration of C-60-PSt in THF solution. (c) 2005 Wiley Periodicals, Inc. |
语种 | 英语 |
WOS记录号 | WOS:000231830500038 |
出版者 | JOHN WILEY & SONS INC |
源URL | [http://ir.iccas.ac.cn/handle/121111/57399] ![]() |
专题 | 中国科学院化学研究所 |
通讯作者 | Hua, J |
作者单位 | 1.Ocean Univ Sci & Technol, Minist Educ, Key Lab Rubber Plast, Qingdao 266042, Peoples R China 2.Chinese Acad Sci, Inst Chem, Beijing 100080, Peoples R China |
推荐引用方式 GB/T 7714 | Hua, J,Yang, HQ,Guo, ZX,et al. Synthesisof C-60-bonded polystyrene initiated with C60Cln/Ni(naph)(2)/P(Ph)(3)[J]. JOURNAL OF APPLIED POLYMER SCIENCE,2005,98(3):1215-1218. |
APA | Hua, J,Yang, HQ,Guo, ZX,Xu, L,&Chen, DB.(2005).Synthesisof C-60-bonded polystyrene initiated with C60Cln/Ni(naph)(2)/P(Ph)(3).JOURNAL OF APPLIED POLYMER SCIENCE,98(3),1215-1218. |
MLA | Hua, J,et al."Synthesisof C-60-bonded polystyrene initiated with C60Cln/Ni(naph)(2)/P(Ph)(3)".JOURNAL OF APPLIED POLYMER SCIENCE 98.3(2005):1215-1218. |
入库方式: OAI收割
来源:化学研究所
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