Synthesis, structure and ethylene oligomerization behavior of non-symmetric bidentate neutral arylnickel(II) phosphine complexes
文献类型：期刊论文
| 作者 | Zhang, YM; Lin, Q; Wei, TB; Zhang, DH; Jie, SY |
| 刊名 | INORGANICA CHIMICA ACTA
 |
| 出版日期 | 2005-12-01 |
| 卷号 | 358期号:15页码:4423-4430 |
| 关键词 | Neutral Nickel(Ii) Complex X-ray Crystallography Catalyst Methylaluminoxane Ethylene Oligomerization |
| ISSN号 | 0020-1693 |
| DOI | 10.1016/j.ica.2005.08.001 |
| 英文摘要 | A series of new neutral arylnickel(II) phosphine complexes bearing non-symmetric bidentate chelate ligands, 3-aryliminomethyl-5cliloro-2-hydi-oxybenzaldehyde, have been synthesized, and the structure of representative complexes (2b and 2d) has been confirmed by X-ray crystallographic analysis. These neutral arylnickel(11) phosphine complexes have been investigated as catalysts for ethylene oligomerization. Using methylaluminoxane (MAO) as a cocatalyst, these complexes display high ethylene oligomerization activities. A catalytic activity of up to 4.6 x 10(6) g mol(-1) h(-1) has been observed. The influence of Al/Ni molar ratio, reaction temperature, reaction period and pressure on catalytic activity was investigated. (c) 2005 Elsevier B.V. All rights reserved. |
| 语种 | 英语 |
| WOS记录号 | WOS:000234041600002 |
| 出版者 | ELSEVIER SCIENCE SA |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/57459]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Zhang, YM |
| 作者单位 | 1.NW Normal Univ, Gansu Key Lab Polymer Mat, Coll Chem & Chem Engn, Lanzhou 730070, Gansu, Peoples R China 2.Chinese Acad Sci, Ctr Mol Sci, Inst Chem, Beijing 100080, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhang, YM,Lin, Q,Wei, TB,et al. Synthesis, structure and ethylene oligomerization behavior of non-symmetric bidentate neutral arylnickel(II) phosphine complexes[J]. INORGANICA CHIMICA ACTA,2005,358(15):4423-4430. |
| APA | Zhang, YM,Lin, Q,Wei, TB,Zhang, DH,&Jie, SY.(2005).Synthesis, structure and ethylene oligomerization behavior of non-symmetric bidentate neutral arylnickel(II) phosphine complexes.INORGANICA CHIMICA ACTA,358(15),4423-4430. |
| MLA | Zhang, YM,et al."Synthesis, structure and ethylene oligomerization behavior of non-symmetric bidentate neutral arylnickel(II) phosphine complexes".INORGANICA CHIMICA ACTA 358.15(2005):4423-4430. |
入库方式： OAI收割
来源：化学研究所
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