Photophysical properties and optical limiting property of a soluble chloroaluminum-phthalocyanine
文献类型：期刊论文
| 作者 | Gan, Q; Li, SY; Morlet-Savary, F; Wang, SQ; Shen, SY; Xu, HJ; Yang, GQ |
| 刊名 | OPTICS EXPRESS
 |
| 出版日期 | 2005-07-11 |
| 卷号 | 13期号:14页码:5424-5433 |
| ISSN号 | 1094-4087 |
| 英文摘要 | A chloroaluminum-phthalocyanine (AlCl-Pc) with tetra-alpha-butoxy chains (AlCl-Pc-OC4) has been synthesized and the photophysical parameters have been determined using steady-state and time-resolved absorption as well as emission spectroscopy. A luminescence from S-2 excited state with long lifetime (5.71 ns) is observed. A multi level model has been proposed to explain the photophysical processes after Soret-band excitation (lambda(ex) = 355nm). The optical limiting performance for 532nm-7ns laser pulses of AlCl-Pc-OC4 has been investigated in THF solution. The sigma(ex) and ratio of sigma(ex)/sigma(0) has been calculated. The good optical limiting performance is attributed to a reverse saturable absorption mechanism. It indicates that AlCl-Pc-OC4 could be promising candidates for optical limiting material. (C) 2005 Optical Society of America. |
| 语种 | 英语 |
| WOS记录号 | WOS:000230519100029 |
| 出版者 | OPTICAL SOC AMER |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/57473]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Gan, Q |
| 作者单位 | 1.Chinese Acad Sci, Inst Chem, Key Lab Photochem, Beijing 100080, Peoples R China 2.Ecole Natl Super Chim, Dept Photochim Gen, CNRS, UMR 7525, F-68093 Mulhouse, France |
| 推荐引用方式 GB/T 7714 | Gan, Q,Li, SY,Morlet-Savary, F,et al. Photophysical properties and optical limiting property of a soluble chloroaluminum-phthalocyanine[J]. OPTICS EXPRESS,2005,13(14):5424-5433. |
| APA | Gan, Q.,Li, SY.,Morlet-Savary, F.,Wang, SQ.,Shen, SY.,...&Yang, GQ.(2005).Photophysical properties and optical limiting property of a soluble chloroaluminum-phthalocyanine.OPTICS EXPRESS,13(14),5424-5433. |
| MLA | Gan, Q,et al."Photophysical properties and optical limiting property of a soluble chloroaluminum-phthalocyanine".OPTICS EXPRESS 13.14(2005):5424-5433. |
入库方式： OAI收割
来源：化学研究所
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