Phase selectively soluble dendritic derivative of 4-(N,N-dimethylamino)pyridine: an easily recyclable catalyst for Baylis-Hillman reactions
文献类型：期刊论文
| 作者 | Yang, NF; Gong, H; Tang, WJ; Fan, QH; Cai, CQ; Yang, LW |
| 刊名 | JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL
 |
| 出版日期 | 2005-05-24 |
| 卷号 | 233期号:1-2页码:55-59 |
| 关键词 | Dendritic Dmap Baylis-hillman Reaction Dendrimer Thermomorphic Biphasic Catalysis Immobilization |
| ISSN号 | 1381-1169 |
| DOI | 10.1016/j.molcata.2005.01.041 |
| 英文摘要 | The Baylis-Hillman reaction of various aryl aldehydes with methyl vinyl ketone and acrylonitrile in the thermomorphic binary system (DMF/cyclohexane, 1/1, v/v) has been investigated. The phase selectively soluble alkyl-modified dendritic DMAP catalyst could be easily recycled via phase separation which was induced by cooling the temperature from 60 degrees C to room temperature. The corresponding Baylis-Hillman adducts were obtained in good yields and the recycled and reactivated dendritic catalyst almost gave the same results. (c) 2005 Elsevier B.V. All rights reserved. |
| 语种 | 英语 |
| WOS记录号 | WOS:000228633100008 |
| 出版者 | ELSEVIER SCIENCE BV |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/57547]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Yang, NF |
| 作者单位 | 1.Xiangtan Univ, Coll Chem, Xiangtan 411105, Peoples R China 2.Chinese Acad Sci, Inst Chem, Ctr Mol Sci, Beijing 100080, Peoples R China |
| 推荐引用方式 GB/T 7714 | Yang, NF,Gong, H,Tang, WJ,et al. Phase selectively soluble dendritic derivative of 4-(N,N-dimethylamino)pyridine: an easily recyclable catalyst for Baylis-Hillman reactions[J]. JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL,2005,233(1-2):55-59. |
| APA | Yang, NF,Gong, H,Tang, WJ,Fan, QH,Cai, CQ,&Yang, LW.(2005).Phase selectively soluble dendritic derivative of 4-(N,N-dimethylamino)pyridine: an easily recyclable catalyst for Baylis-Hillman reactions.JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL,233(1-2),55-59. |
| MLA | Yang, NF,et al."Phase selectively soluble dendritic derivative of 4-(N,N-dimethylamino)pyridine: an easily recyclable catalyst for Baylis-Hillman reactions".JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL 233.1-2(2005):55-59. |
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来源：化学研究所
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