Morphology-driven surface segregation in a blend of poly(epsilon-caprolactone) and poly(vinyl chloride)
文献类型：期刊论文
| 作者 | Cheung, ZL; Weng, LT; Chan, CM; Hou, WM; Li, L |
| 刊名 | LANGMUIR
 |
| 出版日期 | 2005-08-16 |
| 卷号 | 21期号:17页码:7968-7970 |
| ISSN号 | 0743-7463 |
| DOI | 10.1021/la050649n |
| 英文摘要 | A blend of poly(epsilon-caprolactone) (PCL) and poly(vinyl chloride) (PVC) with 90 wt % PCL was prepared. Two films of this blend, which were grown at 35 and 45 degrees C. showed the absence and presence of banded spherulites, respectively. A detailed examination conducted with time-of-flight secondary ion mass spectrometry (ToF-SIMS) found that the surface composition of the film grown at 45 degrees C was related to its structure, which was shown to contain ridges and valleys. Phase images obtained using atomic force microscopy (AFM) indicated that the ridges and valleys consisted of edge-on and flat-on lamellae, respectively. ToF-SIMS imaging revealed that PVC and PCL were located mainly on the surface of the valleys and ridges, respectively. This morphology-driven surface segregation was caused by the difference in the surface energy between the flat-on and edge-on lamellae. |
| 语种 | 英语 |
| WOS记录号 | WOS:000231389200049 |
| 出版者 | AMER CHEMICAL SOC |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/57683]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Chan, CM |
| 作者单位 | 1.Chinese Acad Sci, Inst Chem, Ctr Mol Sci, State Key Lab Polymer Phys & Chem, Beijing 100080, Peoples R China 2.Hong Kong Univ Sci & Technol, Dept Chem Engn & Mat, Hong Kong, Hong Kong, Peoples R China |
| 推荐引用方式 GB/T 7714 | Cheung, ZL,Weng, LT,Chan, CM,et al. Morphology-driven surface segregation in a blend of poly(epsilon-caprolactone) and poly(vinyl chloride)[J]. LANGMUIR,2005,21(17):7968-7970. |
| APA | Cheung, ZL,Weng, LT,Chan, CM,Hou, WM,&Li, L.(2005).Morphology-driven surface segregation in a blend of poly(epsilon-caprolactone) and poly(vinyl chloride).LANGMUIR,21(17),7968-7970. |
| MLA | Cheung, ZL,et al."Morphology-driven surface segregation in a blend of poly(epsilon-caprolactone) and poly(vinyl chloride)".LANGMUIR 21.17(2005):7968-7970. |
入库方式： OAI收割
来源：化学研究所
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