LLDPE preparation by in situ copolymerization of ethylene using matallocene/(2-Me-3-ClPh)(2)PBIMe2FeCl2/MAO tandem catalyzers
文献类型：期刊论文
| 作者 | Wang, RY; Zheng, YS; Cui, NN; Zhang, ZC; Ke, YC; Hu, YL |
| 刊名 | ACTA POLYMERICA SINICA
 |
| 出版日期 | 2005-02-01 |
| 期号 | 1页码:132-136 |
| 关键词 | In Situ Copolymerization Linear Low Density Polyethylene Late Transitional Metal Catalyst |
| ISSN号 | 1000-3304 |
| 英文摘要 | A novel late transitional metal catalyst-(2-Me-3-ClPh)(2)PBIMe2FeCl2-has been synthesized having a high oligomerization activity up to 1.0 x 10(7)g oligomer/( mol Fe (.) It). Using this oligomenization catalyst and metallocene catalyst-rac-C2H4 (Ind)(2)ZrCl2-as a dual functional catalyst system, MAO as the only cocatalyst, Linear Low Density Polyethylene (LLDPE) has been prepared by in situ copolymerization of ethylene having a high activity [> 10(6)g PE/( mol cat (.) h)]. C-13-NMR shows that the LLDPE is obtained. In addition, the presence of unreacted alpha-olefin was not detected since there is no evident resonance signal at 29.29 and 29.42, which proves that this dual functional catalyst system has a good match during in situ copolymerization. With increasing the Fe/Zr ratio, the densities of polymers and the melting points of polymers obtained from DSC are in a descending trend. Meanwhile, the similar phenomenon is also found when the reaction temperature decreases. |
| 语种 | 英语 |
| WOS记录号 | WOS:000226944400026 |
| 出版者 | SCIENCE CHINA PRESS |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/57691]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Wang, RY |
| 作者单位 | 1.Xian Jiaotong Univ, Inst Polymer Composite, Environm & Chem Engn Sch, Xian 710049, Peoples R China 2.Chinese Acad Sci, Inst Chem, Key Lab Engn Plast, Joint Lab Polymer Sci & Mat, Beijing 100080, Peoples R China 3.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wang, RY,Zheng, YS,Cui, NN,et al. LLDPE preparation by in situ copolymerization of ethylene using matallocene/(2-Me-3-ClPh)(2)PBIMe2FeCl2/MAO tandem catalyzers[J]. ACTA POLYMERICA SINICA,2005(1):132-136. |
| APA | Wang, RY,Zheng, YS,Cui, NN,Zhang, ZC,Ke, YC,&Hu, YL.(2005).LLDPE preparation by in situ copolymerization of ethylene using matallocene/(2-Me-3-ClPh)(2)PBIMe2FeCl2/MAO tandem catalyzers.ACTA POLYMERICA SINICA(1),132-136. |
| MLA | Wang, RY,et al."LLDPE preparation by in situ copolymerization of ethylene using matallocene/(2-Me-3-ClPh)(2)PBIMe2FeCl2/MAO tandem catalyzers".ACTA POLYMERICA SINICA .1(2005):132-136. |
入库方式： OAI收割
来源：化学研究所
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