中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
p-nitrophenylazo calix[4]arenes, synthesis, monolayers and NLO-properties

文献类型:期刊论文

作者Guo, X; Zhang, L; Lu, GY; Zhang, CZ; Jin, CM; Liu, MH
刊名SUPRAMOLECULAR CHEMISTRY
出版日期2005-06-01
卷号17期号:4页码:271-276
关键词Calix[4]Arene Nlo Second-order Hyperpolarizability Monolayer
ISSN号1061-0278
DOI10.1080/10610270412331337312
英文摘要The mono, bis, tris and tetrakis (p-nitrophenyl)azo calix[4]arenes (1, 2, 3 and 4) with NLO properties are synthesized by the diazo-coupling of calix[4]arene with p-nitrophenyl diazonium. HRS measurements at 1064 urn indicate that (p-nitrophenyl)azo calix[4]arenes have higher second-order hyperpolarizability beta values than the corresponding reference compound 4-(4-nitrophenylazo)-2,6-dimethylphenol, without red shift of the charge transfer band. The bis and tris (p-nitrophenyl)azo calix[4]arenes (2, 3) without hydrophobic alkyl chains can form stable Langmuri monolayers at the air/water interface because of arene pi-pi stacking.
语种英语
WOS记录号WOS:000230820300001
出版者TAYLOR & FRANCIS LTD
源URL[http://ir.iccas.ac.cn/handle/121111/57741]  
专题中国科学院化学研究所
通讯作者Lu, GY
作者单位1.Nanjing Univ, Dept Chem, State Key Lab Coordinat Chem, Nanjing 210093, Peoples R China
2.Chinese Acad Sci, Inst Chem, Ctr Mol Sci, Lab Colloid & Interface Sci, Beijing 100101, Peoples R China
推荐引用方式
GB/T 7714
Guo, X,Zhang, L,Lu, GY,et al. p-nitrophenylazo calix[4]arenes, synthesis, monolayers and NLO-properties[J]. SUPRAMOLECULAR CHEMISTRY,2005,17(4):271-276.
APA Guo, X,Zhang, L,Lu, GY,Zhang, CZ,Jin, CM,&Liu, MH.(2005).p-nitrophenylazo calix[4]arenes, synthesis, monolayers and NLO-properties.SUPRAMOLECULAR CHEMISTRY,17(4),271-276.
MLA Guo, X,et al."p-nitrophenylazo calix[4]arenes, synthesis, monolayers and NLO-properties".SUPRAMOLECULAR CHEMISTRY 17.4(2005):271-276.

入库方式: OAI收割

来源:化学研究所

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