First experimental observation of gas-phase nitrosyl thiocyanate
文献类型：期刊论文
| 作者 | Yao, Li; Zeng, Xiaoqing; Ge, Maofa; Wang, Weigang; Sun, Zheng; Du, Lin; Wang, Dianxun |
| 刊名 | EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
 |
| 出版日期 | 2006-06-19 |
| 期号 | 12页码:2469-2475 |
| 关键词 | Gas Phase Generation Nitrosyl Thiocyanate Photoelectron Spectroscopy Time-of-flight Mass Spectrometer |
| ISSN号 | 1434-1948 |
| DOI | 10.1002/ejic.200600163 |
| 英文摘要 | The unstable nitrosyl thiocyanate molecule has been generated in the gas phase for the first time from an in situ heterogeneous reaction at low temperature. The product was detected and characterized by a photoelectron spectrometerphotoionization mass spectrometer (PES-PIMS). The electronic and geometric structures of the molecule were investigated with the help of quantum chemical calculations at the B3LYP, CBS-QB3, and CCSD(T) levels. The joint spectroscopic and theoretical studies provided evidence for the formation of nitrosyl thiocyanate, and indicated that the molecule adopts an open-chain, bent structure with the NO and SCN groups bonding by a relatively strong interaction. |
| 语种 | 英语 |
| WOS记录号 | WOS:000238803200016 |
| 出版者 | WILEY-V C H VERLAG GMBH |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/57939]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Ge, Maofa |
| 作者单位 | 1.Chinese Acad Sci, Inst Chem, State Key Lab Struct Chem Unstable & Stable Speci, Beijing 100080, Peoples R China 2.Chinese Acad Sci, Grad Univ, Beijing 100080, Peoples R China |
| 推荐引用方式 GB/T 7714 | Yao, Li,Zeng, Xiaoqing,Ge, Maofa,et al. First experimental observation of gas-phase nitrosyl thiocyanate[J]. EUROPEAN JOURNAL OF INORGANIC CHEMISTRY,2006(12):2469-2475. |
| APA | Yao, Li.,Zeng, Xiaoqing.,Ge, Maofa.,Wang, Weigang.,Sun, Zheng.,...&Wang, Dianxun.(2006).First experimental observation of gas-phase nitrosyl thiocyanate.EUROPEAN JOURNAL OF INORGANIC CHEMISTRY(12),2469-2475. |
| MLA | Yao, Li,et al."First experimental observation of gas-phase nitrosyl thiocyanate".EUROPEAN JOURNAL OF INORGANIC CHEMISTRY .12(2006):2469-2475. |
入库方式： OAI收割
来源：化学研究所
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