中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
4.4'-Bismaleimidodiphenyl methane modified novolak resin/titania nanocomposites: Preparation and properties

文献类型:期刊论文

作者Lu, Guotao; Huang, Ying; Yan, Yehai; Zhao, Tong; Yu, Yunzhao
刊名JOURNAL OF APPLIED POLYMER SCIENCE
出版日期2006-10-05
卷号102期号:1页码:52-57
关键词Nanocomposites Resins Thermal Properties
ISSN号0021-8995
DOI10.1002/app.22116
英文摘要4,4'-Bismaleimidodiphenyl methane modified novolak resin/titania nanocomposites were prepared by the sol-gel process of tetrabutyl titanate in the presence of 4,4'-bismaleimidodiphenyl methane modified novolak resin prepolymers with acetyl acetone as a stabilizer. These nanocomposite materials were characterized by Fourier transform infrared analysis, dynamical mechanical analysis, thermogravimetric analysis, transmission electron microscopy, and field emission scanning electron microscopy. Nanometer titania particles were formed in the novolak resin matrix, and the average original particle size of the dispersed phase in the nanocomposites was less than 150 nm, but particle aggregates of larger size existed. The introduction of the titania inorganic phase with a nanoscale domain size did not improve the glass-transition temperature of the nanocomposites but lowered the thermal resistance of the material because of the incomplete removal of acetyl acetone coordinated with tetrabutyl titanate, and it improved the modulus of the material at lower temperatures (< 200 degrees C) but lowered the modulus at higher temperatures (> 250 degrees C). (c) 2006 Wiley Periodicals, Inc.
语种英语
WOS记录号WOS:000240045000007
出版者JOHN WILEY & SONS INC
源URL[http://ir.iccas.ac.cn/handle/121111/57973]  
专题中国科学院化学研究所
通讯作者Lu, Guotao
作者单位Chinese Acad Sci, Inst Chem, Ctr Mol Sci, Beijing 100080, Peoples R China
推荐引用方式
GB/T 7714
Lu, Guotao,Huang, Ying,Yan, Yehai,et al. 4.4'-Bismaleimidodiphenyl methane modified novolak resin/titania nanocomposites: Preparation and properties[J]. JOURNAL OF APPLIED POLYMER SCIENCE,2006,102(1):52-57.
APA Lu, Guotao,Huang, Ying,Yan, Yehai,Zhao, Tong,&Yu, Yunzhao.(2006).4.4'-Bismaleimidodiphenyl methane modified novolak resin/titania nanocomposites: Preparation and properties.JOURNAL OF APPLIED POLYMER SCIENCE,102(1),52-57.
MLA Lu, Guotao,et al."4.4'-Bismaleimidodiphenyl methane modified novolak resin/titania nanocomposites: Preparation and properties".JOURNAL OF APPLIED POLYMER SCIENCE 102.1(2006):52-57.

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来源:化学研究所

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