Novel hybrid polymer brushes with alternating dendritic wedges and linear side chains
文献类型：期刊论文
| 作者 | Zhang, Yanhong; Li, Xiaokai; Deng, Guohua; Chen, Yongming |
| 刊名 | MACROMOLECULAR CHEMISTRY AND PHYSICS
 |
| 出版日期 | 2006-08-02 |
| 卷号 | 207期号:15页码:1394-1403 |
| 关键词 | Atrp Dendronized Polymer Brushes Graft Copolymers Macromonomers Radical Polymerization |
| ISSN号 | 1022-1352 |
| DOI | 10.1002/macp.200600184 |
| 英文摘要 | Novel hybrid polymer brushes with alternating dendritic wedge and linear chain as side chains were reported in this paper. Firstly, dendronized polymer initiators of generation one to three, GnMIBr (n=1,2,3), were synthesized through the alternating copolymerization of styryl dendrons and maleimide derivative initiated by AIBN. The linear side chains were then generated through grafting-from approach using ATRP of tBA initiated with the above-mentioned macroinitiators. By combining such macromonomers and grafting-from approach, a new kind of polymer brushes with alternating dendron and linear chain as side chains, GnMI-g-PtBA, were thus synthesized and characterized with H-1 NMR, SEC, AFM, etc. Morphology studies made by AFM indicate the polymer brushes display a uniform worm-like structure with a very long contour length. After the hydrolysis of PtBA branches under acidic conditions, amphiphilic dendronized polymer brushes with hydrophilic linear PAA side chains and hydrophobic dendritic side chains of three generations have been prepared. |
| 语种 | 英语 |
| WOS记录号 | WOS:000239848200010 |
| 出版者 | WILEY-V C H VERLAG GMBH |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/58017]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Chen, Yongming |
| 作者单位 | Chinese Acad Sci, Inst Chem, Joint Lab Polymer Sci & Mat, State Key Lab Polymer Phys & Chem, Beijing 100080, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhang, Yanhong,Li, Xiaokai,Deng, Guohua,et al. Novel hybrid polymer brushes with alternating dendritic wedges and linear side chains[J]. MACROMOLECULAR CHEMISTRY AND PHYSICS,2006,207(15):1394-1403. |
| APA | Zhang, Yanhong,Li, Xiaokai,Deng, Guohua,&Chen, Yongming.(2006).Novel hybrid polymer brushes with alternating dendritic wedges and linear side chains.MACROMOLECULAR CHEMISTRY AND PHYSICS,207(15),1394-1403. |
| MLA | Zhang, Yanhong,et al."Novel hybrid polymer brushes with alternating dendritic wedges and linear side chains".MACROMOLECULAR CHEMISTRY AND PHYSICS 207.15(2006):1394-1403. |
入库方式： OAI收割
来源：化学研究所
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