Synthesis, characterization and ethylene oligomerization studies of nickel complexes bearing 2-imino-1,10-phenanthrolines
文献类型：期刊论文
| 作者 | Sun, Wen-Hua ; Zhang, Shu; Jie, Suyun; Zhang, Wen; Li, Yan; Ma, Hongwei; Chen, Jiutong; Wedeking, Katrin; Froehlich, Roland
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| 刊名 | JOURNAL OF ORGANOMETALLIC CHEMISTRY
 |
| 出版日期 | 2006-10-01 |
| 卷号 | 691期号:20页码:4196-4203 |
| 关键词 | Nickel Complexes Ethylene Oligomerization 2-imino-1 10-phenanthrolinyl Ligands |
| ISSN号 | 0022-328X |
| DOI | 10.1016/j.jorganchem.2006.06.028 |
| 英文摘要 | A series of nickel (11) complexes ligated by 2-imino-1,10-phenanthrolines were synthesized and characterized by elemental and spectroscopic analysis as well as by single-crystal X-ray crystallography. X-ray crystallographic analysis reveals complexes 3, 5, 7 and 11 as the five-coordinated distorted trigonal-bipyramidal geometry. Upon activation with Et(2)AlCl, these complexes exhibited considerably high activity for ethylene oligomerization (up to 3.76 x 10(7) g mol(-1) (Ni) h(-1) for 12 with 10 equiv. of PPh(3)). The ligand environment and reaction conditions significantly affect the catalytic activity of their nickel complexes. (c) 2006 Elsevier B.V. All rights reserved. |
| 语种 | 英语 |
| WOS记录号 | WOS:000241213100006 |
| 出版者 | ELSEVIER SCIENCE SA |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/58049]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Sun, Wen-Hua |
| 作者单位 | 1.Chinese Acad Sci, Inst Chem, Key Lab Engn Plast, Beijing 100080, Peoples R China 2.Chinese Acad Sci, Inst Chem, Beijing Natl Lab Mol Sci, Beijing 100080, Peoples R China 3.Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Peoples R China 4.Univ Munster, Inst Organ Chem, D-48149 Munster, Germany |
| 推荐引用方式 GB/T 7714 | Sun, Wen-Hua,Zhang, Shu,Jie, Suyun,et al. Synthesis, characterization and ethylene oligomerization studies of nickel complexes bearing 2-imino-1,10-phenanthrolines[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY,2006,691(20):4196-4203. |
| APA | Sun, Wen-Hua.,Zhang, Shu.,Jie, Suyun.,Zhang, Wen.,Li, Yan.,...&Froehlich, Roland.(2006).Synthesis, characterization and ethylene oligomerization studies of nickel complexes bearing 2-imino-1,10-phenanthrolines.JOURNAL OF ORGANOMETALLIC CHEMISTRY,691(20),4196-4203. |
| MLA | Sun, Wen-Hua,et al."Synthesis, characterization and ethylene oligomerization studies of nickel complexes bearing 2-imino-1,10-phenanthrolines".JOURNAL OF ORGANOMETALLIC CHEMISTRY 691.20(2006):4196-4203. |
入库方式： OAI收割
来源：化学研究所
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