Synthesis of novel maleimide-terminated thioetherimide oligomer and its bulk copolymerization with reactive solvents
文献类型：期刊论文
| 作者 | Liu, F; Wang, Z; Yang, HL; Gao, LX; Ding, MX |
| 刊名 | POLYMER
 |
| 出版日期 | 2006-01-25 |
| 卷号 | 47期号:3页码:937-945 |
| 关键词 | Maleimide-terminated Thioetherimide Oligomer Reactive Solvents Isomeric Effects |
| ISSN号 | 0032-3861 |
| DOI | 10.1016/j.polymer.2005.12.001 |
| 英文摘要 | This paper reports the synthesis of a novel maleimide-terminated thioetherimide oligomer and its copolymefization with reactive solvents bearing vinyl. Starting from 3-chlorophthalic anhydride and 4-chlorophthalic anhydride, 2,2',3,3'-thiodiphenyl tertracaboxylic dianhydride (3,3'-TDPA) and 3,3',4,4'-thiodiphenyl tertracaboxylic dianhydride (4,4'-TDPA) were synthesized. Thereby, a novel maleimide-terminated thioetherimide oligomer was prepared from. 3,3-TDPA, 4,4'-TDPA, 3,3'-dimethyl-4,4-diaminodiphenylmethane (DMMDA) and maleic anhydride. Binary and ternary copolymer resin were derived from corresponding binary and ternary homogeous solution consisting of thioetherimide oligomer, reactive solvent N-vinylpyrrolidone (NVP) or N,N'-dimethylacrylamide (DMAA) and divinylbenzene (DVB) as modifier, initiated either by gamma ray irradiation or by benzoyl peroxide (BPO). Thermal and mechanical properties of copolymer resin are determined and compared in terms of the kind of reactive solvent, addition of modifier DVB. The effect of initiation approach on property of final copolymer resin were studied. Phase separation and sub-transition of ternary copolymer resin induced by BPO are observed, which could be accounted for by thermal movement of DMAA molecules during thermal initiation. Structure-property relationship of copolymer resin was discussed. The effect of monomer molar ratio of 3,3'-TDPA and 4,4'-TDPA on thermal and mechanical properties were investigated. (c) 2005 Elsevier Ltd. All rights reserved. |
| 语种 | 英语 |
| WOS记录号 | WOS:000234935900020 |
| 出版者 | ELSEVIER SCI LTD |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/58229]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Wang, Z |
| 作者单位 | Chinese Acad Sci, Changchun Inst Appl Chem, Grad Sch, State Key Lab Polymer Phys & Chem, Changchun 130022, Peoples R China |
| 推荐引用方式 GB/T 7714 | Liu, F,Wang, Z,Yang, HL,et al. Synthesis of novel maleimide-terminated thioetherimide oligomer and its bulk copolymerization with reactive solvents[J]. POLYMER,2006,47(3):937-945. |
| APA | Liu, F,Wang, Z,Yang, HL,Gao, LX,&Ding, MX.(2006).Synthesis of novel maleimide-terminated thioetherimide oligomer and its bulk copolymerization with reactive solvents.POLYMER,47(3),937-945. |
| MLA | Liu, F,et al."Synthesis of novel maleimide-terminated thioetherimide oligomer and its bulk copolymerization with reactive solvents".POLYMER 47.3(2006):937-945. |
入库方式： OAI收割
来源：化学研究所
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