Do deviations from reptation scaling of entangled polymer melts result from single- or many-chain effects?
文献类型：期刊论文
| 作者 | Liu, Chen-Yang; Keunings, Roland; Bailly, Christian |
| 刊名 | PHYSICAL REVIEW LETTERS
 |
| 出版日期 | 2006-12-15 |
| 卷号 | 97期号:24 |
| ISSN号 | 0031-9007 |
| DOI | 10.1103/PhysRevLett.97.246001 |
| 英文摘要 | By studying the relaxation of small amounts of short entangled "probe" chains in a high molecular weight matrix, we show that the deviations from reptation scaling of the longest relaxation time are not as much dominated by single-chain effects (usually referred to as contour length fluctuations or CLF) as assumed by current mesoscopic models but also originate to a very significant extent from mutual chain relaxation effects. This result is in fact consistent with literature data on tracer and self-diffusion. Moreover, tube theories also overpredict the influence of CLF on the plateau modulus. Improved theories, simulations, and careful experiments are urgently needed to resolve this important question. |
| 语种 | 英语 |
| WOS记录号 | WOS:000242888700046 |
| 出版者 | AMERICAN PHYSICAL SOC |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/58249]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Keunings, Roland |
| 作者单位 | 1.Univ Catholique Louvain, CESAME, B-1348 Louvain, Belgium 2.Univ Catholique Louvain, Unite Chim & Phys Hauts Polymeres, B-1348 Louvain, Belgium 3.Chinese Acad Sci, Inst Chem, Joint Lab Polymer Sci & Mat, Key Lab Engn Plast, Beijing 100080, Peoples R China |
| 推荐引用方式 GB/T 7714 | Liu, Chen-Yang,Keunings, Roland,Bailly, Christian. Do deviations from reptation scaling of entangled polymer melts result from single- or many-chain effects?[J]. PHYSICAL REVIEW LETTERS,2006,97(24). |
| APA | Liu, Chen-Yang,Keunings, Roland,&Bailly, Christian.(2006).Do deviations from reptation scaling of entangled polymer melts result from single- or many-chain effects?.PHYSICAL REVIEW LETTERS,97(24). |
| MLA | Liu, Chen-Yang,et al."Do deviations from reptation scaling of entangled polymer melts result from single- or many-chain effects?".PHYSICAL REVIEW LETTERS 97.24(2006). |
入库方式： OAI收割
来源：化学研究所
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