Synthesis of oxygen-containing heterocyclic compounds based on the intramolecular O-H insertion and Wolff rearrangement of alpha-diazocarbonyl compounds
文献类型:期刊论文
作者 | Liao, Mingyi; Dong, Suwei; Deng, Guisheng; Wang, Jianbo |
刊名 | TETRAHEDRON LETTERS
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出版日期 | 2006-07-03 |
卷号 | 47期号:27页码:4537-4540 |
关键词 | Diazo Compounds Rh(Ii) Carbene Wolff Rearrangement Tetrahydrofuran Derivative Gamma-butyrolactone Derivative |
ISSN号 | 0040-4039 |
DOI | 10.1016/j.tetlet.2006.05.007 |
英文摘要 | The addition products of Ti(IV)-enolate derived from beta-keto alpha(-diazo carbonyl Compound to ketones or alpha,beta-unsaturated compounds were subjected to Rh-2(OAC)(4)-catalyzed and photo-induced diazo decomposition. The Rh-2(OAc)(4)-catalyzed reaction afforded intramolecular O-H insertion products, while the photo-induced reaction gave Wolff rearrangement/intramolecular nucleophilic addition products. The transformations represent new approaches to tetrahydrofuran and gamma-butyrolactone derivatives. (c) 2006 Elsevier Ltd. All rights reserved. |
语种 | 英语 |
WOS记录号 | WOS:000238410400001 |
出版者 | PERGAMON-ELSEVIER SCIENCE LTD |
源URL | [http://ir.iccas.ac.cn/handle/121111/58281] ![]() |
专题 | 中国科学院化学研究所 |
通讯作者 | Wang, Jianbo |
作者单位 | Peking Univ, Coll Chem, Key Lab Bioorgan Chem & Mol Engn Minist Educ, BNLMS, Beijing 100871, Peoples R China |
推荐引用方式 GB/T 7714 | Liao, Mingyi,Dong, Suwei,Deng, Guisheng,et al. Synthesis of oxygen-containing heterocyclic compounds based on the intramolecular O-H insertion and Wolff rearrangement of alpha-diazocarbonyl compounds[J]. TETRAHEDRON LETTERS,2006,47(27):4537-4540. |
APA | Liao, Mingyi,Dong, Suwei,Deng, Guisheng,&Wang, Jianbo.(2006).Synthesis of oxygen-containing heterocyclic compounds based on the intramolecular O-H insertion and Wolff rearrangement of alpha-diazocarbonyl compounds.TETRAHEDRON LETTERS,47(27),4537-4540. |
MLA | Liao, Mingyi,et al."Synthesis of oxygen-containing heterocyclic compounds based on the intramolecular O-H insertion and Wolff rearrangement of alpha-diazocarbonyl compounds".TETRAHEDRON LETTERS 47.27(2006):4537-4540. |
入库方式: OAI收割
来源:化学研究所
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