Chiral supramolecular assemblies from some achiral Schiff bases without alkyl chain through the organization at the air/water interface
文献类型:期刊论文
作者 | Guo, Peizhi; Liu, Minghua |
刊名 | COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS
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出版日期 | 2006-08-15 |
卷号 | 284页码:70-73 |
关键词 | Supramolecular Chirality Aggregate Langmuir-schaefer Film Schiff Base |
ISSN号 | 0927-7757 |
DOI | 10.1016/j.colsurfa.2005.10.093 |
英文摘要 | Two novel Schiff bases, 1-benzthiazolyliminomethyl-2-naphthol (TSN) and 1- (6'-chlorobenzthiazolyliminomethyl)-2-naphthol (CITSN), were synthesized and their molecualr assemblies at the air/water interface were investigated. Both of the compounds could be spread on water surface although they have no alkyl chains. The Schiff base molecules formed J- or H-aggregate in the Langmuir-Schaefer (LS) films transferred from water surface. In AFM, a multilayer film formation was observed. It is interesting to note that the LS films of achiral TSN and CITSN transferred from water surface showed chirality. The supramolecular chirality in these LS films was suggested to be due to a cooperative stereoregular pi-pi stacking of the functional groups in a helical sense. (c) 2005 Elsevier B.V. All rights reserved. |
语种 | 英语 |
WOS记录号 | WOS:000238791800013 |
出版者 | ELSEVIER SCIENCE BV |
源URL | [http://ir.iccas.ac.cn/handle/121111/58337] ![]() |
专题 | 中国科学院化学研究所 |
通讯作者 | Liu, Minghua |
作者单位 | 1.Chinese Acad Sci, Grad Sch, Beijing 100080, Peoples R China 2.Chinese Acad Sci, Inst Chem, CAS Key Lab Colloid Interface & Chem Thermodynam, Beijing 100080, Peoples R China |
推荐引用方式 GB/T 7714 | Guo, Peizhi,Liu, Minghua. Chiral supramolecular assemblies from some achiral Schiff bases without alkyl chain through the organization at the air/water interface[J]. COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS,2006,284:70-73. |
APA | Guo, Peizhi,&Liu, Minghua.(2006).Chiral supramolecular assemblies from some achiral Schiff bases without alkyl chain through the organization at the air/water interface.COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS,284,70-73. |
MLA | Guo, Peizhi,et al."Chiral supramolecular assemblies from some achiral Schiff bases without alkyl chain through the organization at the air/water interface".COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS 284(2006):70-73. |
入库方式: OAI收割
来源:化学研究所
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