中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Chiral supramolecular assemblies from some achiral Schiff bases without alkyl chain through the organization at the air/water interface

文献类型:期刊论文

作者Guo, Peizhi; Liu, Minghua
刊名COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS
出版日期2006-08-15
卷号284页码:70-73
关键词Supramolecular Chirality Aggregate Langmuir-schaefer Film Schiff Base
ISSN号0927-7757
DOI10.1016/j.colsurfa.2005.10.093
英文摘要Two novel Schiff bases, 1-benzthiazolyliminomethyl-2-naphthol (TSN) and 1- (6'-chlorobenzthiazolyliminomethyl)-2-naphthol (CITSN), were synthesized and their molecualr assemblies at the air/water interface were investigated. Both of the compounds could be spread on water surface although they have no alkyl chains. The Schiff base molecules formed J- or H-aggregate in the Langmuir-Schaefer (LS) films transferred from water surface. In AFM, a multilayer film formation was observed. It is interesting to note that the LS films of achiral TSN and CITSN transferred from water surface showed chirality. The supramolecular chirality in these LS films was suggested to be due to a cooperative stereoregular pi-pi stacking of the functional groups in a helical sense. (c) 2005 Elsevier B.V. All rights reserved.
语种英语
WOS记录号WOS:000238791800013
出版者ELSEVIER SCIENCE BV
源URL[http://ir.iccas.ac.cn/handle/121111/58337]  
专题中国科学院化学研究所
通讯作者Liu, Minghua
作者单位1.Chinese Acad Sci, Grad Sch, Beijing 100080, Peoples R China
2.Chinese Acad Sci, Inst Chem, CAS Key Lab Colloid Interface & Chem Thermodynam, Beijing 100080, Peoples R China
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Guo, Peizhi,Liu, Minghua. Chiral supramolecular assemblies from some achiral Schiff bases without alkyl chain through the organization at the air/water interface[J]. COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS,2006,284:70-73.
APA Guo, Peizhi,&Liu, Minghua.(2006).Chiral supramolecular assemblies from some achiral Schiff bases without alkyl chain through the organization at the air/water interface.COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS,284,70-73.
MLA Guo, Peizhi,et al."Chiral supramolecular assemblies from some achiral Schiff bases without alkyl chain through the organization at the air/water interface".COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS 284(2006):70-73.

入库方式: OAI收割

来源:化学研究所

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