Cooperative molecular chirality
文献类型：期刊论文
| 作者 | Shao, Jiushu |
| 刊名 | JOURNAL OF THEORETICAL & COMPUTATIONAL CHEMISTRY
 |
| 出版日期 | 2006 |
| 卷号 | 5页码:331-339 |
| 关键词 | Molecular Chirality Dicke Model Phase Transition |
| ISSN号 | 0219-6336 |
| 英文摘要 | The cooperative chirality for an ensemble of molecules is analyzed with the Dicke model in which the chiral molecules are described by the two-state systems and their interactions are simply characterized by the couplings to external fields due to their collective motion. It is shown that when the temperature is sufficiently low, a phase transition from the achiral state to the chiral one is possible, which is concomitant with emergence of the superradiance. Some physical properties such as the chiralization are calculated in the thermodynamic limit. The results are used to clarify the localization of pyramidal molecules. |
| 语种 | 英语 |
| WOS记录号 | WOS:000240319000005 |
| 出版者 | WORLD SCIENTIFIC PUBL CO PTE LTD |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/58349]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Shao, Jiushu |
| 作者单位 | 1.Beijing Normal Univ, Coll Chem, Beijing 100875, Peoples R China 2.Chinese Acad Sci, Inst Chem, Beijing 100080, Peoples R China |
| 推荐引用方式 GB/T 7714 | Shao, Jiushu. Cooperative molecular chirality[J]. JOURNAL OF THEORETICAL & COMPUTATIONAL CHEMISTRY,2006,5:331-339. |
| APA | Shao, Jiushu.(2006).Cooperative molecular chirality.JOURNAL OF THEORETICAL & COMPUTATIONAL CHEMISTRY,5,331-339. |
| MLA | Shao, Jiushu."Cooperative molecular chirality".JOURNAL OF THEORETICAL & COMPUTATIONAL CHEMISTRY 5(2006):331-339. |
入库方式： OAI收割
来源：化学研究所
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