Effect of ferrous iron concentration on anaerobic bio-hydrogen production from soluble starch
文献类型:期刊论文
作者 | Yang, Haijun; Shen, Jianquan |
刊名 | INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
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出版日期 | 2006-12-01 |
卷号 | 31期号:15页码:2137-2146 |
关键词 | Soluble Starch Anaerobic Bacteria Bio-hydrogen Production Iron Concentration |
ISSN号 | 0360-3199 |
DOI | 10.1016/j.ijhydene.2006.02.009 |
英文摘要 | Both batch experiments (initial pH value was 7.0 and 8.0, respectively) were conducted to convert soluble starch to hydrogen at 35 degrees C. Anaerobic mixed bacteria acclimated with soluble starch was used as inoculum. At initial pH = 8.0, the H-2 yield significantly increased from 106.4 to 274.0 ml/g starch with increasing iron concentration from 0 to 200 mg FeSO4/l. When iron concentration continued to increase from 200 to 4000 mg FeSO4/l, iron inhibition did not happen. On the contrary, hydrogen production was efficiently accelerated. Here, lag-phase time and end time all had about 22 h shortened. However, corresponding cumulative H2 volumes were adjacent to the maximum value (225 ml) required at [FeSO4] = 150 mg/l. As for pH 7.0 systems, though flocculation still appeared, superfluous iron (over 800 mg FeSO4/l) slightly inhibited hydrogen production. The difference in two strains of iron experiments resulted from the variance in initial solubility of iron under various initial pH values. The experiment results show that superfluous soluble iron shows slightly inhibitive influence on H-2 production, and that the optimum soluble iron concentration is 150 mg FeSO4/l from soluble starch (10.0 g/l). Furthermore, the effect of the starch concentration (5.0-40.0 g/l) on hydrogen production also was investigated under 150 mg FeSO4/l. The result shows that high starch concentration has no remarkable effect on H-2 production. The maximum cumulative hydrogen was 260.5 ml at starch concentration of 20 g/l. (c) 2006 International Association for Hydrogen Energy. Published by Elsevier Ltd. All rights reserved. |
语种 | 英语 |
WOS记录号 | WOS:000243291800001 |
出版者 | PERGAMON-ELSEVIER SCIENCE LTD |
源URL | [http://ir.iccas.ac.cn/handle/121111/58393] ![]() |
专题 | 中国科学院化学研究所 |
通讯作者 | Shen, Jianquan |
作者单位 | Chinese Acad Sci, Inst Chem, Lab New Mat, Beijing 100080, Peoples R China |
推荐引用方式 GB/T 7714 | Yang, Haijun,Shen, Jianquan. Effect of ferrous iron concentration on anaerobic bio-hydrogen production from soluble starch[J]. INTERNATIONAL JOURNAL OF HYDROGEN ENERGY,2006,31(15):2137-2146. |
APA | Yang, Haijun,&Shen, Jianquan.(2006).Effect of ferrous iron concentration on anaerobic bio-hydrogen production from soluble starch.INTERNATIONAL JOURNAL OF HYDROGEN ENERGY,31(15),2137-2146. |
MLA | Yang, Haijun,et al."Effect of ferrous iron concentration on anaerobic bio-hydrogen production from soluble starch".INTERNATIONAL JOURNAL OF HYDROGEN ENERGY 31.15(2006):2137-2146. |
入库方式: OAI收割
来源:化学研究所
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