Influence of compressed carbon dioxide on the oxidation of cyclohexane with hydrogen peroxide in acetic acid
文献类型：期刊论文
| 作者 | Gao, L; Jiang, T; Han, BX; Zong, BN; Zhang, XX; Zhang, JC |
| 刊名 | AUSTRALIAN JOURNAL OF CHEMISTRY
 |
| 出版日期 | 2006 |
| 卷号 | 59期号:3页码:225-228 |
| ISSN号 | 0004-9425 |
| DOI | 10.1071/CH05331 |
| 英文摘要 | The oxidation of cyclohexane with H2O2 in a compressed CO2/acetic acid binary system was studied at 60.0 and 80.0 degrees C, at pressures up to 18 MPa, and with the zeolite TS-1 as catalyst. The phase behaviour of the reaction system was also observed. There are three fluid phases in the reaction system at lower pressure but two at higher pressures. In the three-phase region the yields of the products, cyclohexanol and cyclohexanone, increase considerably with increasing pressure and reaches a maximum near the phase-separating pressure. CO2 can thus enhance the reaction effectively. However, the effect of pressure on the yield is very limited after the transition to a two-phase system. |
| 语种 | 英语 |
| WOS记录号 | WOS:000236227700011 |
| 出版者 | CSIRO PUBLISHING |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/58417]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Jiang, T |
| 作者单位 | 1.Chinese Acad Sci, Inst Chem, Ctr Mol Sci, Beijing 100080, Peoples R China 2.Sinopec, Res Inst Petr Proc, Beijing 100083, Peoples R China |
| 推荐引用方式 GB/T 7714 | Gao, L,Jiang, T,Han, BX,et al. Influence of compressed carbon dioxide on the oxidation of cyclohexane with hydrogen peroxide in acetic acid[J]. AUSTRALIAN JOURNAL OF CHEMISTRY,2006,59(3):225-228. |
| APA | Gao, L,Jiang, T,Han, BX,Zong, BN,Zhang, XX,&Zhang, JC.(2006).Influence of compressed carbon dioxide on the oxidation of cyclohexane with hydrogen peroxide in acetic acid.AUSTRALIAN JOURNAL OF CHEMISTRY,59(3),225-228. |
| MLA | Gao, L,et al."Influence of compressed carbon dioxide on the oxidation of cyclohexane with hydrogen peroxide in acetic acid".AUSTRALIAN JOURNAL OF CHEMISTRY 59.3(2006):225-228. |
入库方式： OAI收割
来源：化学研究所
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