Synthesis of polypropylene graft copolymers from a hydroxyl-groups-containing polypropylene precursor via atom-transfer radical polymerization
文献类型：期刊论文
| 作者 | Zhang, LY; Fan, GQ; Guo, CY; Dong, JY; Hu, YL; Huang, MB |
| 刊名 | POLYMER INTERNATIONAL
 |
| 出版日期 | 2006-06-01 |
| 卷号 | 55期号:6页码:675-680 |
| 关键词 | Isotactic Polypropylene Graft Copolymers Hydroxyl Groups Atom Transfer Radical Polymerization (Atrp) |
| ISSN号 | 0959-8103 |
| DOI | 10.1002/pi.2029 |
| 英文摘要 | Isotactic polypropylene graft copolymers, isotactic[polypropylene-graft-poly(methyl methacrylate)] (i-PP-g-PMMA) and isotactic[polypropylene-graft-polystyrene] (i-PP-g-PS), were prepared by atom-transfer radical polymerization (ATRP) using a 2-bromopropionic ester macro-initiator from functional polypropylene-containing hydroxyl groups. This kind of functionalized propylene can be obtained by copolymerization of propylene and borane monomer using isospecific MgCl2-supported TiCl4 as catalyst. Both the graft density and the molecular weights of i-PP-based graft copolymers were controlled by changing the hydroxyl group contents of functionalized polypropylene and the amount of monomer used in the grafting reaction. The effect of i-PP-g-PS graft copolymer on PP-PS blends and that of i-PP-g-PMMA graft copolymer on PP-PMMA blends were studied by scanning electron microscopy. (c) 2006 Society of Chemical Industry. |
| 语种 | 英语 |
| WOS记录号 | WOS:000237548400013 |
| 出版者 | JOHN WILEY & SONS LTD |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/58445]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Dong, JY |
| 作者单位 | 1.Chinese Acad Sci, Inst Chem, Key Lab Engn Plast, Joint Lab Polymer Sci & Mat, Beijing 100080, Peoples R China 2.Grad Univ, Chinese Acad Sci, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhang, LY,Fan, GQ,Guo, CY,et al. Synthesis of polypropylene graft copolymers from a hydroxyl-groups-containing polypropylene precursor via atom-transfer radical polymerization[J]. POLYMER INTERNATIONAL,2006,55(6):675-680. |
| APA | Zhang, LY,Fan, GQ,Guo, CY,Dong, JY,Hu, YL,&Huang, MB.(2006).Synthesis of polypropylene graft copolymers from a hydroxyl-groups-containing polypropylene precursor via atom-transfer radical polymerization.POLYMER INTERNATIONAL,55(6),675-680. |
| MLA | Zhang, LY,et al."Synthesis of polypropylene graft copolymers from a hydroxyl-groups-containing polypropylene precursor via atom-transfer radical polymerization".POLYMER INTERNATIONAL 55.6(2006):675-680. |
入库方式： OAI收割
来源：化学研究所
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