Synthesis, structure, and magnetic properties of hydroxo-bridged vanadium oxalate V2O2(OH)(2)(C2O4)(H2O)(2)
文献类型：期刊论文
| 作者 | Yang, Sihai; Li, Guobao; Tian, Shujian; Liao, Fuhui; Lin, Jianhua |
| 刊名 | EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
 |
| 出版日期 | 2006-07-17 |
| 期号 | 14页码:2850-2854 |
| 关键词 | Vanadium Bridging Ligands Magnetic Properties Dimers Oxalates |
| ISSN号 | 1434-1948 |
| DOI | 10.1002/ejic.200600103 |
| 英文摘要 | The reaction Of V2O5 with H(2)C(2)O(4)(.)2H(2)O in the presence of H3BO3 under hydrothermal conditions has afforded V2O2(OH)(2)(C2O4)(H2O)(2) (1), which crystallizes in the triclinic system, space group P (1) over bar with a = 5.2405(10) angstrom, b = 5.7340(11) angstrom, c = 7.1778(14) angstrom, a = 76.44(3)degrees, beta= 69.37(3)degrees, gamma = 75.37 (3)degrees. The vanadium atoms in I form dimers by sharing edges consisting of p-OH groups, and these dimers are connected further by oxalate ligands to form chains. The magnetic susceptibility data of I fit excellently with the Heisenberg dimer model in the temperature interval 2-300 K. Compound 1 is antiferromagnetic with a J value of -29.6 cm(-1). ((c) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2006). |
| 语种 | 英语 |
| WOS记录号 | WOS:000239292400014 |
| 出版者 | WILEY-V C H VERLAG GMBH |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/58465]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Li, Guobao |
| 作者单位 | Peking Univ, State Key Lab Rare Earth Mat Chem & Applicat, Coll Chem & Mol Engn, BNLMS, Beijing 100871, Peoples R China |
| 推荐引用方式 GB/T 7714 | Yang, Sihai,Li, Guobao,Tian, Shujian,et al. Synthesis, structure, and magnetic properties of hydroxo-bridged vanadium oxalate V2O2(OH)(2)(C2O4)(H2O)(2)[J]. EUROPEAN JOURNAL OF INORGANIC CHEMISTRY,2006(14):2850-2854. |
| APA | Yang, Sihai,Li, Guobao,Tian, Shujian,Liao, Fuhui,&Lin, Jianhua.(2006).Synthesis, structure, and magnetic properties of hydroxo-bridged vanadium oxalate V2O2(OH)(2)(C2O4)(H2O)(2).EUROPEAN JOURNAL OF INORGANIC CHEMISTRY(14),2850-2854. |
| MLA | Yang, Sihai,et al."Synthesis, structure, and magnetic properties of hydroxo-bridged vanadium oxalate V2O2(OH)(2)(C2O4)(H2O)(2)".EUROPEAN JOURNAL OF INORGANIC CHEMISTRY .14(2006):2850-2854. |
入库方式： OAI收割
来源：化学研究所
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