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Chinese Academy of Sciences Institutional Repositories Grid
2D Ln(III)Ru(2)(III) compounds constructed from trans-[Ru(acac)(2)(CN)(2)](-). Syntheses, structures, and magnetic properties

文献类型:期刊论文

作者Yeung, Wai-Fun; Lau, Tai-Chu; Wang, Xin-Yi; Gao, Song; Szeto, Lap; Wong, Wing-Tak
刊名INORGANIC CHEMISTRY
出版日期2006-08-21
卷号45期号:17页码:6756-6760
ISSN号0020-1669
DOI10.1021/ic060580m
英文摘要A series of cyano-bridged Ln(III)Ru(2)(III) coordination polymers, Ph4P {Ln(NO3)(2)[Ru(acac)(2)(CN)(2)](2)} [Ln = Tb (1), Dy (2), Er (3), Gd (4); Hacac = acetylacetone] have been synthesized by the reaction of Ln(NO3)(3) with trans-Ph4P[Ru(acac)(2)(CN)(2)] in methanol. X-ray crystallographic determination reveals that these compounds are isostructural and have a wavy (4,4) layer structure with the Ln(3+) ions bridged by trans-[Ru(acac)(2)(CN)(2)](-). Magnetic studies shows that the magnetic coupling between the Ln( III) and Ru( III) ions through the cyano bridges in 1-4 is negligibly weak.
语种英语
WOS记录号WOS:000239723300035
出版者AMER CHEMICAL SOC
源URL[http://ir.iccas.ac.cn/handle/121111/58537]  
专题中国科学院化学研究所
通讯作者Lau, Tai-Chu
作者单位1.City Univ Hong Kong, Dept Biol & Chem, Kowloon Tong, Hong Kong, Peoples R China
2.Peking Univ, Beijing Natl Lab Mol Sci, State Key Lab Rare Earth Mat Chem & Applicat, Coll Chem & Mol Engn, Beijing 100871, Peoples R China
3.Univ Hong Kong, Dept Chem, Hong Kong, Hong Kong, Peoples R China
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Yeung, Wai-Fun,Lau, Tai-Chu,Wang, Xin-Yi,et al. 2D Ln(III)Ru(2)(III) compounds constructed from trans-[Ru(acac)(2)(CN)(2)](-). Syntheses, structures, and magnetic properties[J]. INORGANIC CHEMISTRY,2006,45(17):6756-6760.
APA Yeung, Wai-Fun,Lau, Tai-Chu,Wang, Xin-Yi,Gao, Song,Szeto, Lap,&Wong, Wing-Tak.(2006).2D Ln(III)Ru(2)(III) compounds constructed from trans-[Ru(acac)(2)(CN)(2)](-). Syntheses, structures, and magnetic properties.INORGANIC CHEMISTRY,45(17),6756-6760.
MLA Yeung, Wai-Fun,et al."2D Ln(III)Ru(2)(III) compounds constructed from trans-[Ru(acac)(2)(CN)(2)](-). Syntheses, structures, and magnetic properties".INORGANIC CHEMISTRY 45.17(2006):6756-6760.

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来源:化学研究所

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