2D Ln(III)Ru(2)(III) compounds constructed from trans-[Ru(acac)(2)(CN)(2)](-). Syntheses, structures, and magnetic properties
文献类型:期刊论文
作者 | Yeung, Wai-Fun; Lau, Tai-Chu; Wang, Xin-Yi; Gao, Song; Szeto, Lap; Wong, Wing-Tak |
刊名 | INORGANIC CHEMISTRY
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出版日期 | 2006-08-21 |
卷号 | 45期号:17页码:6756-6760 |
ISSN号 | 0020-1669 |
DOI | 10.1021/ic060580m |
英文摘要 | A series of cyano-bridged Ln(III)Ru(2)(III) coordination polymers, Ph4P {Ln(NO3)(2)[Ru(acac)(2)(CN)(2)](2)} [Ln = Tb (1), Dy (2), Er (3), Gd (4); Hacac = acetylacetone] have been synthesized by the reaction of Ln(NO3)(3) with trans-Ph4P[Ru(acac)(2)(CN)(2)] in methanol. X-ray crystallographic determination reveals that these compounds are isostructural and have a wavy (4,4) layer structure with the Ln(3+) ions bridged by trans-[Ru(acac)(2)(CN)(2)](-). Magnetic studies shows that the magnetic coupling between the Ln( III) and Ru( III) ions through the cyano bridges in 1-4 is negligibly weak. |
语种 | 英语 |
WOS记录号 | WOS:000239723300035 |
出版者 | AMER CHEMICAL SOC |
源URL | [http://ir.iccas.ac.cn/handle/121111/58537] ![]() |
专题 | 中国科学院化学研究所 |
通讯作者 | Lau, Tai-Chu |
作者单位 | 1.City Univ Hong Kong, Dept Biol & Chem, Kowloon Tong, Hong Kong, Peoples R China 2.Peking Univ, Beijing Natl Lab Mol Sci, State Key Lab Rare Earth Mat Chem & Applicat, Coll Chem & Mol Engn, Beijing 100871, Peoples R China 3.Univ Hong Kong, Dept Chem, Hong Kong, Hong Kong, Peoples R China |
推荐引用方式 GB/T 7714 | Yeung, Wai-Fun,Lau, Tai-Chu,Wang, Xin-Yi,et al. 2D Ln(III)Ru(2)(III) compounds constructed from trans-[Ru(acac)(2)(CN)(2)](-). Syntheses, structures, and magnetic properties[J]. INORGANIC CHEMISTRY,2006,45(17):6756-6760. |
APA | Yeung, Wai-Fun,Lau, Tai-Chu,Wang, Xin-Yi,Gao, Song,Szeto, Lap,&Wong, Wing-Tak.(2006).2D Ln(III)Ru(2)(III) compounds constructed from trans-[Ru(acac)(2)(CN)(2)](-). Syntheses, structures, and magnetic properties.INORGANIC CHEMISTRY,45(17),6756-6760. |
MLA | Yeung, Wai-Fun,et al."2D Ln(III)Ru(2)(III) compounds constructed from trans-[Ru(acac)(2)(CN)(2)](-). Syntheses, structures, and magnetic properties".INORGANIC CHEMISTRY 45.17(2006):6756-6760. |
入库方式: OAI收割
来源:化学研究所
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