Chemical reaction and energy transfer between hot H atoms and CO2 molecules
文献类型：期刊论文
| 作者 | Shi, Cong-yun; Ren, Li; Kong, Fan-ao |
| 刊名 | CHINESE JOURNAL OF CHEMICAL PHYSICS
 |
| 出版日期 | 2006-12-27 |
| 卷号 | 19期号:6页码:473-477 |
| 关键词 | Energy Transfer h Atom Co2 Molecule |
| ISSN号 | 1003-7713 |
| DOI | 10.1360/cjcp2006.19(6).473.5 |
| 英文摘要 | Collisions between hot H atoms and CO2 molecules were studied experimentally by time-resolved Fourier transform infrared emission spectroscopy. H atoms with three translational energies, 174.7, 241.0 and 306.2 kJ/mol respectively, were generated by UV laser photolysis to initiate a chemical reaction of H+CO2 -> OH+CO. Vibrationally excited CO (v <= 2) was observed in the spectrum, where CO was the product of the reaction. The highly efficient T-V energy transfer from the hot H atoms to the CO2 was verified too. The highest vibrational level of v=4 in CO2 (v(3)) was found. Rate ratio of the chemical reaction to the energy transfer was estimated as 10. |
| 语种 | 英语 |
| WOS记录号 | WOS:000243370300002 |
| 出版者 | SCIENCE CHINA PRESS |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/58565]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Kong, Fan-ao |
| 作者单位 | Chinese Acad Sci, Inst Chem, Beijing 100080, Peoples R China |
| 推荐引用方式 GB/T 7714 | Shi, Cong-yun,Ren, Li,Kong, Fan-ao. Chemical reaction and energy transfer between hot H atoms and CO2 molecules[J]. CHINESE JOURNAL OF CHEMICAL PHYSICS,2006,19(6):473-477. |
| APA | Shi, Cong-yun,Ren, Li,&Kong, Fan-ao.(2006).Chemical reaction and energy transfer between hot H atoms and CO2 molecules.CHINESE JOURNAL OF CHEMICAL PHYSICS,19(6),473-477. |
| MLA | Shi, Cong-yun,et al."Chemical reaction and energy transfer between hot H atoms and CO2 molecules".CHINESE JOURNAL OF CHEMICAL PHYSICS 19.6(2006):473-477. |
入库方式： OAI收割
来源：化学研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。