One-pot synthesis of polyetherimides from bis(chlorophthalimide) and dichlorodiphenylsulfone in diphenylsulfone
文献类型:期刊论文
作者 | Shang, Zhenping; Lu, Changli; Zhao, Jianying; Yan, Jingling; Ding, Mengxian; Gao, Lianxun |
刊名 | JOURNAL OF APPLIED POLYMER SCIENCE
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出版日期 | 2006-12-05 |
卷号 | 102期号:5页码:4584-4588 |
关键词 | Polyetherimide Bis(Chlorophthalimide) Diphenylsulfone Dichlorodiphenylsulfone One-pot Synthesis |
ISSN号 | 0021-8995 |
DOI | 10.1002/app.25051 |
英文摘要 | Polyetherimides and copolymers have been synthesized in one pot from bis(chlorophthalimide), dichlorodiphenylsulfone, and bisphenolate using diphenylsulfone as the solvent. The inherent viscosities of the obtained polyimides are in the range of 0.32-0.72 dL/g, and the structures of polyimides were confirmed by IR and elemental analyses. All of the polyimides have good solubility in common organic solvents. The 5% weight-loss temperatures of the polyimides were 429-507 C in air. The glass transition temperatures (T3) of 4,4'-(9-fluorenylidene) diphenol-based polyimides are in the range of 253-268 degrees C. The Tg of bisphenol A-based polyimides is in the range of 198204 degrees C, while the T-g change inconspicuously when the ratios of diphenylsulfone increase. The wide-angle X-ray diffraction showed that all polyimides prepared are amorphous. (c) 2006 Wiley Periodicals, Inc. |
语种 | 英语 |
WOS记录号 | WOS:000241593700066 |
出版者 | JOHN WILEY & SONS INC |
源URL | [http://ir.iccas.ac.cn/handle/121111/58607] ![]() |
专题 | 中国科学院化学研究所 |
通讯作者 | Gao, Lianxun |
作者单位 | Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Polymer Phys & Chem, Grad Sch, Changchun 130022, Peoples R China |
推荐引用方式 GB/T 7714 | Shang, Zhenping,Lu, Changli,Zhao, Jianying,et al. One-pot synthesis of polyetherimides from bis(chlorophthalimide) and dichlorodiphenylsulfone in diphenylsulfone[J]. JOURNAL OF APPLIED POLYMER SCIENCE,2006,102(5):4584-4588. |
APA | Shang, Zhenping,Lu, Changli,Zhao, Jianying,Yan, Jingling,Ding, Mengxian,&Gao, Lianxun.(2006).One-pot synthesis of polyetherimides from bis(chlorophthalimide) and dichlorodiphenylsulfone in diphenylsulfone.JOURNAL OF APPLIED POLYMER SCIENCE,102(5),4584-4588. |
MLA | Shang, Zhenping,et al."One-pot synthesis of polyetherimides from bis(chlorophthalimide) and dichlorodiphenylsulfone in diphenylsulfone".JOURNAL OF APPLIED POLYMER SCIENCE 102.5(2006):4584-4588. |
入库方式: OAI收割
来源:化学研究所
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