中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Morphology transition of bismaleimide-modified novolac resin

文献类型:期刊论文

作者Lu, Guotao; Huang, Ying; Yan, Yehai; Zhao, Tong; Yu, Yunzhao
刊名JOURNAL OF APPLIED POLYMER SCIENCE
出版日期2006-10-05
卷号102期号:1页码:76-83
关键词Novolac Resin Preparation Morphology Phase Separation Thermal Properties
ISSN号0021-8995
DOI10.1002/app.22601
英文摘要The bismaleimide (BMI)-modified novolac resin was synthesized by allylation of the novolac resin and its "Ene" reaction with BMI. The reactions were monitored by Fourier transform infrared analysis (FTIR). The morphology of the BMI-modified novolac resin changed with degree of allylation (i.e., the amount of BMI used). On the basis of the studies done by dynamical mechanical analysis (DMA), differential scanning calorimetry (DSC), and field emission scanning electron microscopy (FE-SEM), it was found that when the degree of allylation increased from 48 to 59%, the resin changed from a single-phase structure to a two-phase structure. From the research by thermogravimetric analysis (TGA) and DMA, it was found that the higher allyl-content (when > 48%) caused a decrease of the thermal properties and mechanical properties of the resultant resin. The BMI-modified allyl novolac resin with 48% degree of allylation has the best thermal properties and the highest dynamic modulus in the current research. (c) 2006 Wiley Periodicals, Inc.
语种英语
WOS记录号WOS:000240045000010
出版者JOHN WILEY & SONS INC
源URL[http://ir.iccas.ac.cn/handle/121111/58699]  
专题中国科学院化学研究所
通讯作者Lu, Guotao
作者单位Chinese Acad Sci, Inst Chem, Ctr Mol Sci, Beijing 100080, Peoples R China
推荐引用方式
GB/T 7714
Lu, Guotao,Huang, Ying,Yan, Yehai,et al. Morphology transition of bismaleimide-modified novolac resin[J]. JOURNAL OF APPLIED POLYMER SCIENCE,2006,102(1):76-83.
APA Lu, Guotao,Huang, Ying,Yan, Yehai,Zhao, Tong,&Yu, Yunzhao.(2006).Morphology transition of bismaleimide-modified novolac resin.JOURNAL OF APPLIED POLYMER SCIENCE,102(1),76-83.
MLA Lu, Guotao,et al."Morphology transition of bismaleimide-modified novolac resin".JOURNAL OF APPLIED POLYMER SCIENCE 102.1(2006):76-83.

入库方式: OAI收割

来源:化学研究所

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