Morphology and thermal behavior of MCPA6/SAN blends prepared by anionic ring-opening polymerization of epsilon-caprolactam
文献类型：期刊论文
| 作者 | Hou, LL; Yang, G |
| 刊名 | JOURNAL OF APPLIED POLYMER SCIENCE
 |
| 出版日期 | 2006-04-15 |
| 卷号 | 100期号:2页码:1357-1363 |
| 关键词 | Monomer Casting Polyamide 6 Styrene-acrylonitrile Anionic Ring-opening Polymerization Morphology Crystallization Properties |
| ISSN号 | 0021-8995 |
| 英文摘要 | In this article, a series of blends of monomer casting polyamide 6 and styrene-co-acrylonitrile (MCPA6/ SAN) were prepared by in situ anionic ring-opening polymerization of B-caprolactam. Their morphology and thermal behaviors were investigated by means of scanning electron microscope, differential scanning calorimeter, and wide-angle X-ray diffraction (WAXD), respectively. The SAN phase had much finer domain in MCPA6/SAN than that in the PA6/SAN blends prepared by melt blending of PA6 and SAN. All the melting and crystallization parameters of MCPA6/SAN blends decreased gradually with the increase of SAN content, while the melting temperature was almost unchanged. These results were due to the hydrolysis reaction of SAN that occurred during the anionic polymerization of e-caprolactam. In addition, WAXD results showed that only a crystal forms existed in the MCPA6/SAN blends. In addition, the mechanical property of MCPA6 was improved obviously by incorporating a certain amount of SAN. |
| 语种 | 英语 |
| WOS记录号 | WOS:000235556400062 |
| 出版者 | JOHN WILEY & SONS INC |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/58723]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Hou, LL |
| 作者单位 | 1.Chinese Acad Sci, Inst Chem, CAS Key Lab Engn Plast, Joint Lab Polymer Sci & Mat, Beijing 100080, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China 3.Shanghai Genius Adv Mat Co Ltd, Shanghai 201109, Peoples R China |
| 推荐引用方式 GB/T 7714 | Hou, LL,Yang, G. Morphology and thermal behavior of MCPA6/SAN blends prepared by anionic ring-opening polymerization of epsilon-caprolactam[J]. JOURNAL OF APPLIED POLYMER SCIENCE,2006,100(2):1357-1363. |
| APA | Hou, LL,&Yang, G.(2006).Morphology and thermal behavior of MCPA6/SAN blends prepared by anionic ring-opening polymerization of epsilon-caprolactam.JOURNAL OF APPLIED POLYMER SCIENCE,100(2),1357-1363. |
| MLA | Hou, LL,et al."Morphology and thermal behavior of MCPA6/SAN blends prepared by anionic ring-opening polymerization of epsilon-caprolactam".JOURNAL OF APPLIED POLYMER SCIENCE 100.2(2006):1357-1363. |
入库方式： OAI收割
来源：化学研究所
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