Direct electrochemistry of multi-copper oxidases at carbon nanotubes noncovalently functionalized with cellulose derivatives
文献类型：期刊论文
| 作者 | Zheng, W; Li, QF; Su, L; Yan, YM; Zhang, J; Mao, LQ |
| 刊名 | ELECTROANALYSIS
 |
| 出版日期 | 2006-03-01 |
| 卷号 | 18期号:6页码:587-594 |
| 关键词 | Carbon Nanotubes Multi-copper Oxidases Direct Electron Transfer O-2 Reduction Ascorbate/o-2 Biofuel Cell |
| ISSN号 | 1040-0397 |
| DOI | 10.1002/elan.200503444 |
| 英文摘要 | This study describes the direct electron transfer of multi-copper oxidases, i.e., laccase (from Trametes versicolor) and bilirubin oxidase (BOD, from Myrothecium verrucaria) at multiwalled carbon nanotubes (MWNTs) noncovalently functionalized with biopolymers of Cellulose derivatives, i.e., hydroxyethyl cellulose (HEC), methyl cellulose (MC), and carboxymethyl Cellulose (CIVIC). The functionalization of the MWNTs with the Cellulose derivatives is found to substantially solubilize the MWNTs into aqueous' media and to avoid their aggregation oil electrode Surface. Under anaerobic conditions, the redox properties of laccase and BOD are difficult to be defined with cyclic voltammetry at either laccase/MWNT modified or BOD/MWNT-modified electrodes. The direct electron transfer properties of laccase and BOD are thus Studied in terms of the bioelectrocatalytic activities of the laccase/MWNT-modified and BOD/MWNT-modified electrodes toward the reduction of oxygen and found to be facilitated at the functionalized MWNTs. The possible application of the laccase-catalyzed O-2 reduction at the laccase/MWNT-modified electrode is illustrated by constructing CNT-based ascorbate/O-2 biofuel cell with the MWNT-modified electrode as the anode for the oxidation of ascorbate biofuel. |
| 语种 | 英语 |
| WOS记录号 | WOS:000236288700006 |
| 出版者 | WILEY-V C H VERLAG GMBH |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/58725]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Mao, LQ |
| 作者单位 | 1.Chinese Acad Sci, Inst Chem, Ctr Mol Sci, Beijing 100080, Peoples R China 2.Harbin Engn Univ, Sch Mech & Elect Engn, Harbin 150001, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zheng, W,Li, QF,Su, L,et al. Direct electrochemistry of multi-copper oxidases at carbon nanotubes noncovalently functionalized with cellulose derivatives[J]. ELECTROANALYSIS,2006,18(6):587-594. |
| APA | Zheng, W,Li, QF,Su, L,Yan, YM,Zhang, J,&Mao, LQ.(2006).Direct electrochemistry of multi-copper oxidases at carbon nanotubes noncovalently functionalized with cellulose derivatives.ELECTROANALYSIS,18(6),587-594. |
| MLA | Zheng, W,et al."Direct electrochemistry of multi-copper oxidases at carbon nanotubes noncovalently functionalized with cellulose derivatives".ELECTROANALYSIS 18.6(2006):587-594. |
入库方式： OAI收割
来源：化学研究所
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