中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Ionization and dissociation of nitrosyl chloride molecule in the intense femtosecond laser field

文献类型:期刊论文

作者Yao Li; Ge Mao-Fa; Wang Dian-Xun; Wu Cheng-Yin; Xu Nan; Gong Qi-Huang
刊名CHINESE JOURNAL OF CHEMISTRY
出版日期2006-07-01
卷号24期号:7页码:867-871
关键词Nitrosyl Chloride Intense Femtosecond Laser Field Electronic Structure Calculation Ionization Dissociation
ISSN号1001-604X
英文摘要Ionization and dissociation of nitrosyl chloride CINO were studied using femtosecond laser mass spectra technique. Strong fragmental ions NO+ and Cl+ were observed with the laser intensity varied from 3.2 X 10(14) to 2.5 X 10(15) W/cm(2). These fragmental ions were attributed to the direct dissociation of the parent ions. Electronic structure calculations were also carried out with Hartree-Fock, density functional and correlated levels of theory to understand the possible fragmentation pathways. The very low N-Cl bond energy in the parent ion of nitrosyl chloride is a clear reason for the absence of ClNO+ and ClN+ ion peaks from the femtosecond laser mass spectrum.
语种英语
WOS记录号WOS:000239053100007
出版者WILEY-V C H VERLAG GMBH
源URL[http://ir.iccas.ac.cn/handle/121111/58815]  
专题中国科学院化学研究所
通讯作者Yao Li
作者单位1.Chinese Acad Sci, Inst Chem, Beijing Natl Lab Mol Sci, Beijing 100080, Peoples R China
2.Peking Univ, Dept Phys, State Key Lab Mesoscop Phys, Beijing 100871, Peoples R China
推荐引用方式
GB/T 7714
Yao Li,Ge Mao-Fa,Wang Dian-Xun,et al. Ionization and dissociation of nitrosyl chloride molecule in the intense femtosecond laser field[J]. CHINESE JOURNAL OF CHEMISTRY,2006,24(7):867-871.
APA Yao Li,Ge Mao-Fa,Wang Dian-Xun,Wu Cheng-Yin,Xu Nan,&Gong Qi-Huang.(2006).Ionization and dissociation of nitrosyl chloride molecule in the intense femtosecond laser field.CHINESE JOURNAL OF CHEMISTRY,24(7),867-871.
MLA Yao Li,et al."Ionization and dissociation of nitrosyl chloride molecule in the intense femtosecond laser field".CHINESE JOURNAL OF CHEMISTRY 24.7(2006):867-871.

入库方式: OAI收割

来源:化学研究所

浏览0
下载0
收藏0
其他版本

除非特别说明,本系统中所有内容都受版权保护,并保留所有权利。