Ionization and dissociation of nitrosyl chloride molecule in the intense femtosecond laser field
文献类型:期刊论文
作者 | Yao Li; Ge Mao-Fa; Wang Dian-Xun; Wu Cheng-Yin; Xu Nan; Gong Qi-Huang |
刊名 | CHINESE JOURNAL OF CHEMISTRY
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出版日期 | 2006-07-01 |
卷号 | 24期号:7页码:867-871 |
关键词 | Nitrosyl Chloride Intense Femtosecond Laser Field Electronic Structure Calculation Ionization Dissociation |
ISSN号 | 1001-604X |
英文摘要 | Ionization and dissociation of nitrosyl chloride CINO were studied using femtosecond laser mass spectra technique. Strong fragmental ions NO+ and Cl+ were observed with the laser intensity varied from 3.2 X 10(14) to 2.5 X 10(15) W/cm(2). These fragmental ions were attributed to the direct dissociation of the parent ions. Electronic structure calculations were also carried out with Hartree-Fock, density functional and correlated levels of theory to understand the possible fragmentation pathways. The very low N-Cl bond energy in the parent ion of nitrosyl chloride is a clear reason for the absence of ClNO+ and ClN+ ion peaks from the femtosecond laser mass spectrum. |
语种 | 英语 |
WOS记录号 | WOS:000239053100007 |
出版者 | WILEY-V C H VERLAG GMBH |
源URL | [http://ir.iccas.ac.cn/handle/121111/58815] ![]() |
专题 | 中国科学院化学研究所 |
通讯作者 | Yao Li |
作者单位 | 1.Chinese Acad Sci, Inst Chem, Beijing Natl Lab Mol Sci, Beijing 100080, Peoples R China 2.Peking Univ, Dept Phys, State Key Lab Mesoscop Phys, Beijing 100871, Peoples R China |
推荐引用方式 GB/T 7714 | Yao Li,Ge Mao-Fa,Wang Dian-Xun,et al. Ionization and dissociation of nitrosyl chloride molecule in the intense femtosecond laser field[J]. CHINESE JOURNAL OF CHEMISTRY,2006,24(7):867-871. |
APA | Yao Li,Ge Mao-Fa,Wang Dian-Xun,Wu Cheng-Yin,Xu Nan,&Gong Qi-Huang.(2006).Ionization and dissociation of nitrosyl chloride molecule in the intense femtosecond laser field.CHINESE JOURNAL OF CHEMISTRY,24(7),867-871. |
MLA | Yao Li,et al."Ionization and dissociation of nitrosyl chloride molecule in the intense femtosecond laser field".CHINESE JOURNAL OF CHEMISTRY 24.7(2006):867-871. |
入库方式: OAI收割
来源:化学研究所
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