Ionization and dissociation of nitrosyl chloride molecule in the intense femtosecond laser field
文献类型：期刊论文
| 作者 | Yao Li; Ge Mao-Fa; Wang Dian-Xun; Wu Cheng-Yin; Xu Nan; Gong Qi-Huang |
| 刊名 | CHINESE JOURNAL OF CHEMISTRY
 |
| 出版日期 | 2006-07-01 |
| 卷号 | 24期号:7页码:867-871 |
| 关键词 | Nitrosyl Chloride Intense Femtosecond Laser Field Electronic Structure Calculation Ionization Dissociation |
| ISSN号 | 1001-604X |
| 英文摘要 | Ionization and dissociation of nitrosyl chloride CINO were studied using femtosecond laser mass spectra technique. Strong fragmental ions NO+ and Cl+ were observed with the laser intensity varied from 3.2 X 10(14) to 2.5 X 10(15) W/cm(2). These fragmental ions were attributed to the direct dissociation of the parent ions. Electronic structure calculations were also carried out with Hartree-Fock, density functional and correlated levels of theory to understand the possible fragmentation pathways. The very low N-Cl bond energy in the parent ion of nitrosyl chloride is a clear reason for the absence of ClNO+ and ClN+ ion peaks from the femtosecond laser mass spectrum. |
| 语种 | 英语 |
| WOS记录号 | WOS:000239053100007 |
| 出版者 | WILEY-V C H VERLAG GMBH |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/58815]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Yao Li |
| 作者单位 | 1.Chinese Acad Sci, Inst Chem, Beijing Natl Lab Mol Sci, Beijing 100080, Peoples R China 2.Peking Univ, Dept Phys, State Key Lab Mesoscop Phys, Beijing 100871, Peoples R China |
| 推荐引用方式 GB/T 7714 | Yao Li,Ge Mao-Fa,Wang Dian-Xun,et al. Ionization and dissociation of nitrosyl chloride molecule in the intense femtosecond laser field[J]. CHINESE JOURNAL OF CHEMISTRY,2006,24(7):867-871. |
| APA | Yao Li,Ge Mao-Fa,Wang Dian-Xun,Wu Cheng-Yin,Xu Nan,&Gong Qi-Huang.(2006).Ionization and dissociation of nitrosyl chloride molecule in the intense femtosecond laser field.CHINESE JOURNAL OF CHEMISTRY,24(7),867-871. |
| MLA | Yao Li,et al."Ionization and dissociation of nitrosyl chloride molecule in the intense femtosecond laser field".CHINESE JOURNAL OF CHEMISTRY 24.7(2006):867-871. |
入库方式： OAI收割
来源：化学研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。