Novel layered calcosilicate-immobilized iron-based diimine catalyst for ethylene polymerization
文献类型：期刊论文
| 作者 | Xu, H; Guo, CY; Xue, CF; Ma, Z; Zhang, MG; Dong, JX; Wang, JG; Hu, YL |
| 刊名 | EUROPEAN POLYMER JOURNAL
 |
| 出版日期 | 2006 |
| 卷号 | 42期号:1页码:203-208 |
| 关键词 | Calcosilicate Immobilization Iron-based Diimine Catalyst Ethylene Polymerization |
| ISSN号 | 0014-3057 |
| DOI | 10.1016/j.eurpolymj.2005.07.020 |
| 英文摘要 | A novel layered calcosilicate (CAS-1) was employed to immobilize an iron-based diimine catalyst 2,6-bis[1-(2,6-diisopropylphenylimino)ethyl]pyridine iron chloride (1) onto it to form a supported catalyst (CC) for the first time. The crystal structure of CAS-I was determined by X-ray crystallographic analysis in addition to SEM characterization. The CC-catalyzed ethylene polymerization exhibited good catalytic activities with either co-catalyst methylaluminoxane (MAO) or triethylaluminum (TEA). The resulting polyethylenes possessed not only higher molecular weight, melting temperature (T-m), and decomposition onset temperature (T-onset) than those obtained with its homogeneous counterpart, but also a unique morphology. (c) 2005 Elsevier Ltd. All rights reserved. |
| 语种 | 英语 |
| WOS记录号 | WOS:000234817700023 |
| 出版者 | PERGAMON-ELSEVIER SCIENCE LTD |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/58903]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Guo, CY |
| 作者单位 | 1.Chinese Acad Sci, Key Lab Engn Plast, Joint Lab Polymer Sci & Mat, Inst Chem, Beijing 100080, Peoples R China 2.Taiyuna Univ Technol, Res Inst Special Chem, Taiyuan 030024, Peoples R China 3.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China 4.Chinese Acad Sci, Inst Coal Chem, State Key Lab Coal Convers, Taiyuan 030001, Peoples R China |
| 推荐引用方式 GB/T 7714 | Xu, H,Guo, CY,Xue, CF,et al. Novel layered calcosilicate-immobilized iron-based diimine catalyst for ethylene polymerization[J]. EUROPEAN POLYMER JOURNAL,2006,42(1):203-208. |
| APA | Xu, H.,Guo, CY.,Xue, CF.,Ma, Z.,Zhang, MG.,...&Hu, YL.(2006).Novel layered calcosilicate-immobilized iron-based diimine catalyst for ethylene polymerization.EUROPEAN POLYMER JOURNAL,42(1),203-208. |
| MLA | Xu, H,et al."Novel layered calcosilicate-immobilized iron-based diimine catalyst for ethylene polymerization".EUROPEAN POLYMER JOURNAL 42.1(2006):203-208. |
入库方式： OAI收割
来源：化学研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。