A simple method to generate B(N-3)(3)
文献类型:期刊论文
作者 | Liu, FY; Zeng, XQ; Zhang, HP; Meng, LP; Zheng, SJ; Ge, MF; Wang, DX; Mok, DKW; Chau, FT |
刊名 | CHEMICAL PHYSICS LETTERS
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出版日期 | 2006-02-15 |
卷号 | 419期号:1-3页码:213-216 |
ISSN号 | 0009-2614 |
DOI | 10.1016/j.cplett.2005.11.082 |
英文摘要 | Boron triazide, B(N-3)(3), is first generated in gas phase by the heterogeneous reaction of BBr3 vapor with freshly synthesized AgN3 powder at room temperature. Identification of B(N-3)(3) has been achieved by combination of photoelectron spectroscopy with the outer valence Green's function calculation. B(N-3)(3) is a planar molecule with C-3h, symmetry and has the first adiabatic ionization energy of 11.39 eV. Vibrational spacings 2200 +/- 60 cm(-1) and 1250 +/- 60 cm(-1) on the first and third bands match well to the N-3 asymmetric stretch and the B-N stretching vibrations in the neutral B(N-3)(3) molecule, respectively. (c) 2005 Elsevier B.V. All rights reserved. |
语种 | 英语 |
WOS记录号 | WOS:000235438900042 |
出版者 | ELSEVIER SCIENCE BV |
源URL | [http://ir.iccas.ac.cn/handle/121111/58939] ![]() |
专题 | 中国科学院化学研究所 |
通讯作者 | Ge, MF |
作者单位 | 1.Hebei Normal Univ, Open Lab Computat Quantum Chem, Shijiazhuang 050091, Peoples R China 2.Chinese Acad Sci, State Key Lab Struct Chem Unstable & Stable Speci, Inst Chem, Beijing 100080, Haidian, Peoples R China 3.Hong Kong Polytech Univ, Dept Appl Biol & Chem Technol, Hong Kong, Hong Kong, Peoples R China |
推荐引用方式 GB/T 7714 | Liu, FY,Zeng, XQ,Zhang, HP,et al. A simple method to generate B(N-3)(3)[J]. CHEMICAL PHYSICS LETTERS,2006,419(1-3):213-216. |
APA | Liu, FY.,Zeng, XQ.,Zhang, HP.,Meng, LP.,Zheng, SJ.,...&Chau, FT.(2006).A simple method to generate B(N-3)(3).CHEMICAL PHYSICS LETTERS,419(1-3),213-216. |
MLA | Liu, FY,et al."A simple method to generate B(N-3)(3)".CHEMICAL PHYSICS LETTERS 419.1-3(2006):213-216. |
入库方式: OAI收割
来源:化学研究所
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