The crystal structure of hexaammonium diacetyl-octa-molybdate tetrahydrate
文献类型:期刊论文
作者 | Xiao, ZC; Wei, YG; Xu, L; Wang, Y |
刊名 | CRYSTAL RESEARCH AND TECHNOLOGY
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出版日期 | 2006-06-01 |
卷号 | 41期号:6页码:595-599 |
关键词 | Diacetyl-octamolybdate(Vi) Polyoxometalates Crystal Structure |
ISSN号 | 0232-1300 |
DOI | 10.1002/crat.200510631 |
英文摘要 | The crystal structure of hexaammonium diacetyl-octa-molybdate tetrahydrate, (NH4)(42)[Mo132O372 (CH3COO)(30)(H2O)(72)] is documented. The crystals are triclinic, space group P-1, with a=8.1018(16) angstrom, b=10.334(2) angstrom, c=12.238(2) angstrom, alpha=68.20(3)degrees, beta=74.98(3)degrees, gamma=67.25(3)degrees, V=869.3(3) angstrom, Z=1. The structure. was solved by direct methods and refined by least squares methods to a Final R1 = 0.0374 and wR2 = 0. 1074 for 3805 observed reflections with I > 2 sigma(I). The structure contains ammonium cations and isolated acetyl octamolybdate(6-)anions, [Mo8O28(CH3CO)(2)](6-). The crystallographic data of the structure was deposited with the Cambridge Data Center as No. CCDC 249565. (c) 2006 WILEYNCH Verlag GmbH & Co. KGaA, Weinheim. |
语种 | 英语 |
WOS记录号 | WOS:000238682900011 |
出版者 | WILEY-V C H VERLAG GMBH |
源URL | [http://ir.iccas.ac.cn/handle/121111/59019] ![]() |
专题 | 中国科学院化学研究所 |
通讯作者 | Wei, YG |
作者单位 | 1.Peking Univ, State Key Lab Struct Chem Unstable & Stable Speci, Inst Phys Chem, Coll Chem & Mol Engn, Beijing 100871, Peoples R China 2.NE Normal Univ, Dept Chem, Changchun 130024, Peoples R China |
推荐引用方式 GB/T 7714 | Xiao, ZC,Wei, YG,Xu, L,et al. The crystal structure of hexaammonium diacetyl-octa-molybdate tetrahydrate[J]. CRYSTAL RESEARCH AND TECHNOLOGY,2006,41(6):595-599. |
APA | Xiao, ZC,Wei, YG,Xu, L,&Wang, Y.(2006).The crystal structure of hexaammonium diacetyl-octa-molybdate tetrahydrate.CRYSTAL RESEARCH AND TECHNOLOGY,41(6),595-599. |
MLA | Xiao, ZC,et al."The crystal structure of hexaammonium diacetyl-octa-molybdate tetrahydrate".CRYSTAL RESEARCH AND TECHNOLOGY 41.6(2006):595-599. |
入库方式: OAI收割
来源:化学研究所
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