Effect of side-chain substituents on self-assembly of perylene diimide molecules: Morphology control
文献类型：期刊论文
| 作者 | Balakrishnan, K; Datar, A; Naddo, T; Huang, JL; Oitker, R; Yen, M; Zhao, JC; Zang, L |
| 刊名 | JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
 |
| 出版日期 | 2006-06-07 |
| 卷号 | 128期号:22页码:7390-7398 |
| ISSN号 | 0002-7863 |
| DOI | 10.1021/ja061810z |
| 英文摘要 | Effect of side-chain substitutions on the morphology of self-assembly of perylene diimide molecules has been studied with two derivatives modified with distinctly different side-chains, N, N'-di( dodecyl)-perylene-3,4,9,10-tetracarboxylic diimide ( DD-PTCDI) and N, N'-di( nonyldecyl)-perylene-3,4,9,10-tetracarboxylic diimide ( ND-PTCDI). Due to the different side-chain interference, the self-assembly of the two molecules results in totally different morphologies in aggregate: one-dimensional ( 1D) nanobelt vs zero-dimensional ( 0D) nanoparticle. The size, shape, and topography of the self-assemblies were extensively characterized by a variety of microscopies including SEM, TEM, AFM, and fluorescence microscopy. The distinct morphologies of self-assembly have been obtained from both the solution-based processing and surface-supported solvent-vapor annealing. The nanobelts of DD-PTCDI fabricated in solution can feasibly be transferred to both polar ( e. g., glass) and nonpolar ( e. g., carbon) surfaces, implying the high stability of the molecular assembly ( due to the strong pi-pi stacking). The side-chain-dependent molecular interaction was comparatively investigated using various spectrometries including UV-vis absorption, fluorescence, X-ray diffraction, and differential scanning calorimetry. Compared to the emission of ND-PTCDI aggregate, the emission of DD-PTCDI aggregate was significantly red-shifted ( ca. 30 nm) and the emission quantum yield decreased about three times, primarily due to the more favorable molecular stacking for DD-PTCID. Moreover, the aggregate of DD-PTCDI shows a pronounced absorption band at the longer wavelength, whereas the absorption of ND-PTCDI aggregate is not significant in the same wavelength region. These optical spectral observations are reminiscent of the previous theoretical investigation on the side-chain-modulated electronic properties of PTCDI assembly. |
| 语种 | 英语 |
| WOS记录号 | WOS:000237931700060 |
| 出版者 | AMER CHEMICAL SOC |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/59073]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Zang, L |
| 作者单位 | 1.So Illinois Univ, Dept Chem & Biochem, Carbondale, IL 62901 USA 2.So Illinois Univ, MTC, Carbondale, IL 62901 USA 3.Chinese Acad Sci, Inst Chem, Key Lab Photochem, Beijing 100080, Peoples R China |
| 推荐引用方式 GB/T 7714 | Balakrishnan, K,Datar, A,Naddo, T,et al. Effect of side-chain substituents on self-assembly of perylene diimide molecules: Morphology control[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY,2006,128(22):7390-7398. |
| APA | Balakrishnan, K.,Datar, A.,Naddo, T.,Huang, JL.,Oitker, R.,...&Zang, L.(2006).Effect of side-chain substituents on self-assembly of perylene diimide molecules: Morphology control.JOURNAL OF THE AMERICAN CHEMICAL SOCIETY,128(22),7390-7398. |
| MLA | Balakrishnan, K,et al."Effect of side-chain substituents on self-assembly of perylene diimide molecules: Morphology control".JOURNAL OF THE AMERICAN CHEMICAL SOCIETY 128.22(2006):7390-7398. |
入库方式： OAI收割
来源：化学研究所
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