Determination of rate constants for ozone reactions with acetylene under atmospheric conditions
文献类型：期刊论文
| 作者 | Du Lin; Xu Yong-Fu; Ge Mao-Fa; Jia Long; Wang Geng-Chen; Wang Dian-Xun |
| 刊名 | ACTA CHIMICA SINICA
 |
| 出版日期 | 2006-11-14 |
| 卷号 | 64期号:21页码:2133-2137 |
| ISSN号 | 0567-7351 |
| 关键词 | Ozone Acetylene Kinetics Rate Constant |
| 英文摘要 | Ozone is an important oxidant in the troposphere, and its reactions with reactive gases are important processes in the troposphere, which has a significance for the research on countermeasures of air pollution. The simulative reaction equipment of smog chamber, made in our laboratory, was used to study ozone reactions with acetylene in terms of monitoring instruments of ozone analyzer and gas chromatography. A mean value of 4.13 x 10(-21) cm(3).molecule(-1).s(-1) for rate constant was obtained from four experiments under room temperature of about 15 degrees C. Its variant coefficient is 7%. Our rate constant is within the range reported by other researchers using different experimental conditions and detecting methods. Results show that the precision of determination of rate constants is high from our experiments. Our self-made simulation system of smog chamber for atmospheric reactions is reliable, which can be applied to deep research of other ozone reactions under atmospheric ozone concentrations. Our results and experimental system provide a good basis for further research on chemical reactions of other important reactive gases in the atmosphere. |
| 语种 | 英语 |
| 出版者 | SCIENCE CHINA PRESS |
| WOS记录号 | WOS:000241999400001 |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/59087]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Du Lin |
| 作者单位 | 1.Chinese Acad Sci, Inst Chem, Beijing Natl Lab Mol Sci, Beijing 100080, Peoples R China 2.Chinese Acad Sci, Inst Atmospher Phys, State Key Lab Atmospher Boundary Layer Phys & Atm, Beijing 100029, Peoples R China 3.Beijing Normal Univ, Res Ctr Atmospher Environm, Beijing 100875, Peoples R China 4.Chinese Acad Sci, Inst Atmospher Phys, Div Middle Atmosphere & Remote Sensing, Beijing 100029, Peoples R China |
| 推荐引用方式 GB/T 7714 | Du Lin,Xu Yong-Fu,Ge Mao-Fa,et al. Determination of rate constants for ozone reactions with acetylene under atmospheric conditions[J]. ACTA CHIMICA SINICA,2006,64(21):2133-2137. |
| APA | Du Lin,Xu Yong-Fu,Ge Mao-Fa,Jia Long,Wang Geng-Chen,&Wang Dian-Xun.(2006).Determination of rate constants for ozone reactions with acetylene under atmospheric conditions.ACTA CHIMICA SINICA,64(21),2133-2137. |
| MLA | Du Lin,et al."Determination of rate constants for ozone reactions with acetylene under atmospheric conditions".ACTA CHIMICA SINICA 64.21(2006):2133-2137. |
入库方式： OAI收割
来源：化学研究所
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