Effect of glass bead packing on the fibrillation of liquid-crystalline polymer in polycarbonate
文献类型：期刊论文
| 作者 | Chen, P; Chen, J; Zhang, BQ; Zhang, J; He, JS |
| 刊名 | JOURNAL OF POLYMER SCIENCE PART B-POLYMER PHYSICS
 |
| 出版日期 | 2006-03-15 |
| 卷号 | 44期号:6页码:1020-1030 |
| 关键词 | Fillers Liquid-crystalline Polymers (Lcp) Morphology Polycarbonates Rheology |
| ISSN号 | 0887-6266 |
| DOI | 10.1002/polb.20755 |
| 英文摘要 | Polycarbonate (PC) was melt blended with small amount of liquid-crystalline polymer (LCP) and various contents of glass beads (GB) having different diameters. The rheological measurements indicated that the GB addition increased the viscosity ratio and seemed unfavorable to the LCP fibrillation. However, the morphological observation showed that the LCP fibrillation was promoted by the GB addition and varied with the GB packing. With the increased GB packing by increasing the GB content and/or decreasing the GB diameter, LCP deformed from spheres and ellipsoids into stretched ellipsoids at lower shear rates and into long fibrils at higher shear rates. Although higher content of smaller GB jammed into the larger LCP droplets and inhibited the LCP fibrillation, very long LCP fibrils formed at higher shear rates at a high enough packing of GB. The relationship between GB packing and LCP fibrillation revealed two kinds of hydrodynamic effects of GB promoting the LCP fibrillation: at lower GB packing, the shear flow was enhanced by the high local shear between GB, in quantity; and for a high enough GB packing, the shear flow was changed, in quality, into elongational flow, which was more effective for the LCP fibrillation. (c) 2006 Wiley Periodicals, Inc. |
| 语种 | 英语 |
| WOS记录号 | WOS:000235727500013 |
| 出版者 | JOHN WILEY & SONS INC |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/59097]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | He, JS |
| 作者单位 | 1.Chinese Acad Sci, Inst Chem, Key Lab Engn Plast, Joint Lab Polymer Sci & Mat, Beijing 100080, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China |
| 推荐引用方式 GB/T 7714 | Chen, P,Chen, J,Zhang, BQ,et al. Effect of glass bead packing on the fibrillation of liquid-crystalline polymer in polycarbonate[J]. JOURNAL OF POLYMER SCIENCE PART B-POLYMER PHYSICS,2006,44(6):1020-1030. |
| APA | Chen, P,Chen, J,Zhang, BQ,Zhang, J,&He, JS.(2006).Effect of glass bead packing on the fibrillation of liquid-crystalline polymer in polycarbonate.JOURNAL OF POLYMER SCIENCE PART B-POLYMER PHYSICS,44(6),1020-1030. |
| MLA | Chen, P,et al."Effect of glass bead packing on the fibrillation of liquid-crystalline polymer in polycarbonate".JOURNAL OF POLYMER SCIENCE PART B-POLYMER PHYSICS 44.6(2006):1020-1030. |
入库方式： OAI收割
来源：化学研究所
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