Highly enantioselective borane reduction of prochiral ketones catalyzed by C-3-symmetric tripodal beta-hydroxy amides
文献类型：期刊论文
| 作者 | Fang, Tao; Xu, Jiaxi; Du, Da-Ming |
| 刊名 | SYNLETT
 |
| 出版日期 | 2006-06-11 |
| 期号 | 10页码:1559-1563 |
| 关键词 | Asymmetric Reduction Borane Ketone Beta-hydroxyamide C-3 Symmetry |
| ISSN号 | 0936-5214 |
| DOI | 10.1055/s-2006-94159 |
| 英文摘要 | The asymmetric borane reduction of prochiral ketones with a series of easily constructed chiral C-3-symmetric tripodal tris(beta-hydroxyamide) ligands was investigated. The borane complex of chiral ligand 1,1',1"-(1,3,5-benzenetricarbonyl)-tris[(2S)-alpha,alpha-diphenl-2-pyrrolidinemethanol] (1h) was found to be an efficient catalyst in asymmetric borane reduction of prochiral ketones and excellent enantioselectivities were obtained with both electron-deficient and electron-rich prochiral ketones (up to 97% ee). |
| 语种 | 英语 |
| WOS记录号 | WOS:000238732100021 |
| 出版者 | GEORG THIEME VERLAG KG |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/59221]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Du, Da-Ming |
| 作者单位 | Peking Univ, Coll Chem & Mol Engn, Key Lab Bioorgan Chem & Mol Engn, Beijing Natl Lab Mol Sci, Beijing 100871, Peoples R China |
| 推荐引用方式 GB/T 7714 | Fang, Tao,Xu, Jiaxi,Du, Da-Ming. Highly enantioselective borane reduction of prochiral ketones catalyzed by C-3-symmetric tripodal beta-hydroxy amides[J]. SYNLETT,2006(10):1559-1563. |
| APA | Fang, Tao,Xu, Jiaxi,&Du, Da-Ming.(2006).Highly enantioselective borane reduction of prochiral ketones catalyzed by C-3-symmetric tripodal beta-hydroxy amides.SYNLETT(10),1559-1563. |
| MLA | Fang, Tao,et al."Highly enantioselective borane reduction of prochiral ketones catalyzed by C-3-symmetric tripodal beta-hydroxy amides".SYNLETT .10(2006):1559-1563. |
入库方式： OAI收割
来源：化学研究所
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