Synthesis and characterization of ABC ternary segregated H-shaped copolymers
文献类型:期刊论文
作者 | Xu, Kui; Wang, Yun; Wang, Yanxue; Yu, Tao; An, LiJia; Pan, Caiyuan; Bai, Ruke |
刊名 | POLYMER
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出版日期 | 2006-06-14 |
卷号 | 47期号:13页码:4480-4484 |
关键词 | Abc Ternary Copolymer Atom Transfer Radical Polymerization Segregated H-shaped Polymer |
ISSN号 | 0032-3861 |
DOI | 10.1016/j.polymer.2006.04.064 |
英文摘要 | The synthesis of a novel ABC ternary segregated H-shaped copolymer is described, of which a central poly(ethylene glycol) (PEG) chain is terminated on both sides by polystyrene (PS) and poly(tert-butylacrylate) (PtBA) chains. The synthetic procedure involves functionalization of PEG by 2-bromosuccinic anhydride followed by esterification of 1,6-hexanediol, which gives its ends the bifunctional nature that allows sequential growth of two PS, then two PtBA arms via atom transfer radical polymerization (ATRP). The resulting segregated H-shaped copolymers were characterization by NMR spectroscopy and gel permeation chromatography (GPC). All these copolymers were affirmed to have well-defined structures and narrow molecular weight distributions. (c) 2006 Elsevier Ltd. All rights reserved. |
语种 | 英语 |
WOS记录号 | WOS:000238921300002 |
出版者 | ELSEVIER SCI LTD |
源URL | [http://ir.iccas.ac.cn/handle/121111/59319] ![]() |
专题 | 中国科学院化学研究所 |
通讯作者 | Bai, Ruke |
作者单位 | 1.Univ Sci & Technol China, Dept Polymer Sci & Engn, Hefei 230026, Peoples R China 2.Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Polymer Phys & Chem, Changchun 130022, Peoples R China |
推荐引用方式 GB/T 7714 | Xu, Kui,Wang, Yun,Wang, Yanxue,et al. Synthesis and characterization of ABC ternary segregated H-shaped copolymers[J]. POLYMER,2006,47(13):4480-4484. |
APA | Xu, Kui.,Wang, Yun.,Wang, Yanxue.,Yu, Tao.,An, LiJia.,...&Bai, Ruke.(2006).Synthesis and characterization of ABC ternary segregated H-shaped copolymers.POLYMER,47(13),4480-4484. |
MLA | Xu, Kui,et al."Synthesis and characterization of ABC ternary segregated H-shaped copolymers".POLYMER 47.13(2006):4480-4484. |
入库方式: OAI收割
来源:化学研究所
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