中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Synthesis and characterization of ABC ternary segregated H-shaped copolymers

文献类型:期刊论文

作者Xu, Kui; Wang, Yun; Wang, Yanxue; Yu, Tao; An, LiJia; Pan, Caiyuan; Bai, Ruke
刊名POLYMER
出版日期2006-06-14
卷号47期号:13页码:4480-4484
关键词Abc Ternary Copolymer Atom Transfer Radical Polymerization Segregated H-shaped Polymer
ISSN号0032-3861
DOI10.1016/j.polymer.2006.04.064
英文摘要The synthesis of a novel ABC ternary segregated H-shaped copolymer is described, of which a central poly(ethylene glycol) (PEG) chain is terminated on both sides by polystyrene (PS) and poly(tert-butylacrylate) (PtBA) chains. The synthetic procedure involves functionalization of PEG by 2-bromosuccinic anhydride followed by esterification of 1,6-hexanediol, which gives its ends the bifunctional nature that allows sequential growth of two PS, then two PtBA arms via atom transfer radical polymerization (ATRP). The resulting segregated H-shaped copolymers were characterization by NMR spectroscopy and gel permeation chromatography (GPC). All these copolymers were affirmed to have well-defined structures and narrow molecular weight distributions. (c) 2006 Elsevier Ltd. All rights reserved.
语种英语
WOS记录号WOS:000238921300002
出版者ELSEVIER SCI LTD
源URL[http://ir.iccas.ac.cn/handle/121111/59319]  
专题中国科学院化学研究所
通讯作者Bai, Ruke
作者单位1.Univ Sci & Technol China, Dept Polymer Sci & Engn, Hefei 230026, Peoples R China
2.Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Polymer Phys & Chem, Changchun 130022, Peoples R China
推荐引用方式
GB/T 7714
Xu, Kui,Wang, Yun,Wang, Yanxue,et al. Synthesis and characterization of ABC ternary segregated H-shaped copolymers[J]. POLYMER,2006,47(13):4480-4484.
APA Xu, Kui.,Wang, Yun.,Wang, Yanxue.,Yu, Tao.,An, LiJia.,...&Bai, Ruke.(2006).Synthesis and characterization of ABC ternary segregated H-shaped copolymers.POLYMER,47(13),4480-4484.
MLA Xu, Kui,et al."Synthesis and characterization of ABC ternary segregated H-shaped copolymers".POLYMER 47.13(2006):4480-4484.

入库方式: OAI收割

来源:化学研究所

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