Synthesis, crystal structure, and magnetic properties of a three-dimensional cyano-bridged bimetallic coordination polymer with an aromatic amine capping ligand: [Cu(2,2 '-dpa)](3)[Cr(CN)6](2)center dot 3H(2)O (2,2 '-dpa=2,2 '-dipicolylamine)
文献类型：期刊论文
| 作者 | Liu, CM; Gao, S; Kou, HZ; Zhang, DQ; Sun, HL; Zhu, DB |
| 刊名 | CRYSTAL GROWTH & DESIGN
 |
| 出版日期 | 2006 |
| 卷号 | 6期号:1页码:94-98 |
| ISSN号 | 1528-7483 |
| DOI | 10.1021/cg050186j |
| 英文摘要 | A three-dimensional (3D) Cu(II)-containing Prussian Blue analogue with two types of [Cr(CN)(6)](3-) units, [Cu(2,2'-dpa)](3)[Cr(CN)(6)](2)center dot 3H(2)O (2,2'-dpa = 2,2'-dipicolylamine), was synthesized and characterized. One type of [Cr(CN)(6)](3-) unit in this complex coordinates to six copper(II) atoms to form the heptanuclear [CrCu6] unit, which connects with other [CrCu6] units through the other type of [Cr(CN)(6)](3-) unit acting as bidentate spacer link only. Magnetic investigations of this complex revealed that long-range ferromagnetic ordering occurs below the Curie temperature of 3 K. It is the first example of 3D complex-based Prussian Blue analogues containing aromatic amine capping ligands. |
| 语种 | 英语 |
| WOS记录号 | WOS:000234723700021 |
| 出版者 | AMER CHEMICAL SOC |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/59343]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Liu, CM |
| 作者单位 | 1.Chinese Acad Sci, Inst Chem, Ctr Mol Sci, Beijing Natl Lab Mol Sci, Beijing 100080, Peoples R China 2.Peking Univ, Coll Chem & Mol Engn, State Key Lab Rare Earth Mat & Applicat, Beijing 100871, Peoples R China 3.Tsing Hua Univ, Dept Chem, Beijing 100084, Peoples R China |
| 推荐引用方式 GB/T 7714 | Liu, CM,Gao, S,Kou, HZ,et al. Synthesis, crystal structure, and magnetic properties of a three-dimensional cyano-bridged bimetallic coordination polymer with an aromatic amine capping ligand: [Cu(2,2 '-dpa)](3)[Cr(CN)6](2)center dot 3H(2)O (2,2 '-dpa=2,2 '-dipicolylamine)[J]. CRYSTAL GROWTH & DESIGN,2006,6(1):94-98. |
| APA | Liu, CM,Gao, S,Kou, HZ,Zhang, DQ,Sun, HL,&Zhu, DB.(2006).Synthesis, crystal structure, and magnetic properties of a three-dimensional cyano-bridged bimetallic coordination polymer with an aromatic amine capping ligand: [Cu(2,2 '-dpa)](3)[Cr(CN)6](2)center dot 3H(2)O (2,2 '-dpa=2,2 '-dipicolylamine).CRYSTAL GROWTH & DESIGN,6(1),94-98. |
| MLA | Liu, CM,et al."Synthesis, crystal structure, and magnetic properties of a three-dimensional cyano-bridged bimetallic coordination polymer with an aromatic amine capping ligand: [Cu(2,2 '-dpa)](3)[Cr(CN)6](2)center dot 3H(2)O (2,2 '-dpa=2,2 '-dipicolylamine)".CRYSTAL GROWTH & DESIGN 6.1(2006):94-98. |
入库方式： OAI收割
来源：化学研究所
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