中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Synthesis, crystal structure, and magnetic properties of a three-dimensional cyano-bridged bimetallic coordination polymer with an aromatic amine capping ligand: [Cu(2,2 '-dpa)](3)[Cr(CN)6](2)center dot 3H(2)O (2,2 '-dpa=2,2 '-dipicolylamine)

文献类型:期刊论文

作者Liu, CM; Gao, S; Kou, HZ; Zhang, DQ; Sun, HL; Zhu, DB
刊名CRYSTAL GROWTH & DESIGN
出版日期2006
卷号6期号:1页码:94-98
ISSN号1528-7483
DOI10.1021/cg050186j
英文摘要A three-dimensional (3D) Cu(II)-containing Prussian Blue analogue with two types of [Cr(CN)(6)](3-) units, [Cu(2,2'-dpa)](3)[Cr(CN)(6)](2)center dot 3H(2)O (2,2'-dpa = 2,2'-dipicolylamine), was synthesized and characterized. One type of [Cr(CN)(6)](3-) unit in this complex coordinates to six copper(II) atoms to form the heptanuclear [CrCu6] unit, which connects with other [CrCu6] units through the other type of [Cr(CN)(6)](3-) unit acting as bidentate spacer link only. Magnetic investigations of this complex revealed that long-range ferromagnetic ordering occurs below the Curie temperature of 3 K. It is the first example of 3D complex-based Prussian Blue analogues containing aromatic amine capping ligands.
语种英语
WOS记录号WOS:000234723700021
出版者AMER CHEMICAL SOC
源URL[http://ir.iccas.ac.cn/handle/121111/59343]  
专题中国科学院化学研究所
通讯作者Liu, CM
作者单位1.Chinese Acad Sci, Inst Chem, Ctr Mol Sci, Beijing Natl Lab Mol Sci, Beijing 100080, Peoples R China
2.Peking Univ, Coll Chem & Mol Engn, State Key Lab Rare Earth Mat & Applicat, Beijing 100871, Peoples R China
3.Tsing Hua Univ, Dept Chem, Beijing 100084, Peoples R China
推荐引用方式
GB/T 7714
Liu, CM,Gao, S,Kou, HZ,et al. Synthesis, crystal structure, and magnetic properties of a three-dimensional cyano-bridged bimetallic coordination polymer with an aromatic amine capping ligand: [Cu(2,2 '-dpa)](3)[Cr(CN)6](2)center dot 3H(2)O (2,2 '-dpa=2,2 '-dipicolylamine)[J]. CRYSTAL GROWTH & DESIGN,2006,6(1):94-98.
APA Liu, CM,Gao, S,Kou, HZ,Zhang, DQ,Sun, HL,&Zhu, DB.(2006).Synthesis, crystal structure, and magnetic properties of a three-dimensional cyano-bridged bimetallic coordination polymer with an aromatic amine capping ligand: [Cu(2,2 '-dpa)](3)[Cr(CN)6](2)center dot 3H(2)O (2,2 '-dpa=2,2 '-dipicolylamine).CRYSTAL GROWTH & DESIGN,6(1),94-98.
MLA Liu, CM,et al."Synthesis, crystal structure, and magnetic properties of a three-dimensional cyano-bridged bimetallic coordination polymer with an aromatic amine capping ligand: [Cu(2,2 '-dpa)](3)[Cr(CN)6](2)center dot 3H(2)O (2,2 '-dpa=2,2 '-dipicolylamine)".CRYSTAL GROWTH & DESIGN 6.1(2006):94-98.

入库方式: OAI收割

来源:化学研究所

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