Photoelectron Spectroscopy and UV absorption spectroscopy studies on some nitrogen catenation compounds
文献类型：期刊论文
| 作者 | Sun, Z; Zeng, XQ; Wang, WG; Ge, MF; Wang, DX |
| 刊名 | ACTA CHIMICA SINICA
 |
| 出版日期 | 2006-02-14 |
| 卷号 | 64期号:3页码:218-222 |
| 关键词 | High Energy Material Nitrogen Catenation Photoelectron Spectroscopy Uv Absorption Spectroscopy Quantum Chemistry Calculation |
| ISSN号 | 0567-7351 |
| 英文摘要 | Compounds with a backbone of directly linked nitrogen atoms have high nitrogen concentration and high formation enthalpy. The end product of a propulsion or explosion of these compounds contained mainly molecular nitrogen. Therefore, the study on them as potential environment-friendly propellants and explosives was of great interest recently. In this paper, the ionization potentials of 1H-tetrazole (1), 5-aminotetrazole (2), 1,5-diaminotetrazole (3) and 1,4-bis(1-methyltetrazol-5-yl)-1,4-dimethyl-2-tetrazene (4) were reported, which were recorded by photoelectron spectroscopy. The experiment gave the ionization potentials of the four compounds as 11.22, 9.40, 9.27, 9.18 eV respectively. The UV absorption spectra showed that there was only one absorption band in compounds 1 similar to 3, at 193, 216, 218 mn respectively, while compound 4 had two UV absorption bands at 230 and 298 nm. |
| 语种 | 英语 |
| WOS记录号 | WOS:000235385200006 |
| 出版者 | SCIENCE PRESS |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/59353]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Sun, Z |
| 作者单位 | Chinese Acad Sci, Inst Chem, Beijing 100080, Peoples R China |
| 推荐引用方式 GB/T 7714 | Sun, Z,Zeng, XQ,Wang, WG,et al. Photoelectron Spectroscopy and UV absorption spectroscopy studies on some nitrogen catenation compounds[J]. ACTA CHIMICA SINICA,2006,64(3):218-222. |
| APA | Sun, Z,Zeng, XQ,Wang, WG,Ge, MF,&Wang, DX.(2006).Photoelectron Spectroscopy and UV absorption spectroscopy studies on some nitrogen catenation compounds.ACTA CHIMICA SINICA,64(3),218-222. |
| MLA | Sun, Z,et al."Photoelectron Spectroscopy and UV absorption spectroscopy studies on some nitrogen catenation compounds".ACTA CHIMICA SINICA 64.3(2006):218-222. |
入库方式： OAI收割
来源：化学研究所
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