New approaches to polysubstituted pyrroles and gamma-lactams based on nucleophilic addition of Ti(IV) enolates derived from alpha-diazo-beta-keto carbonyl compounds to N-tosylimines
文献类型：期刊论文
| 作者 | Dong, Changqing; Deng, Guisheng; Wang, Jianbo |
| 刊名 | JOURNAL OF ORGANIC CHEMISTRY
 |
| 出版日期 | 2006-07-21 |
| 卷号 | 71期号:15页码:5560-5564 |
| ISSN号 | 0022-3263 |
| DOI | 10.1021/jo0605039 |
| 英文摘要 | The Ti(IV) enolates derived from alpha-diazo-beta- keto esters or ketones efficiently add to TiCl4- activated N-tosylimines to give delta-N-tosylamino substituted alpha-diazo-beta-keto carbonyl compounds. The diazo decomposition of the addition products occurs under Rh-2(OAc)(4)-catalyzed or photoinduced conditions to afford pyrrole or gamma-lactam derivatives, both in high yields. |
| 语种 | 英语 |
| WOS记录号 | WOS:000239017500016 |
| 出版者 | AMER CHEMICAL SOC |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/59367]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Wang, Jianbo |
| 作者单位 | 1.Peking Univ, BNLMS, Key Lab Bioorgan Chem, Beijing 100871, Peoples R China 2.Peking Univ, Coll Chem, Mol Engn Minist Educ, Beijing 100871, Peoples R China |
| 推荐引用方式 GB/T 7714 | Dong, Changqing,Deng, Guisheng,Wang, Jianbo. New approaches to polysubstituted pyrroles and gamma-lactams based on nucleophilic addition of Ti(IV) enolates derived from alpha-diazo-beta-keto carbonyl compounds to N-tosylimines[J]. JOURNAL OF ORGANIC CHEMISTRY,2006,71(15):5560-5564. |
| APA | Dong, Changqing,Deng, Guisheng,&Wang, Jianbo.(2006).New approaches to polysubstituted pyrroles and gamma-lactams based on nucleophilic addition of Ti(IV) enolates derived from alpha-diazo-beta-keto carbonyl compounds to N-tosylimines.JOURNAL OF ORGANIC CHEMISTRY,71(15),5560-5564. |
| MLA | Dong, Changqing,et al."New approaches to polysubstituted pyrroles and gamma-lactams based on nucleophilic addition of Ti(IV) enolates derived from alpha-diazo-beta-keto carbonyl compounds to N-tosylimines".JOURNAL OF ORGANIC CHEMISTRY 71.15(2006):5560-5564. |
入库方式： OAI收割
来源：化学研究所
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