Structural effects on the Langmuir monolayers of calix[4]arene induced by lower rim aromatic substitution
文献类型：期刊论文
| 作者 | He Wei-Jiang; Qiu Lin; Li Jun-Bai; Zhang Yu; Guo Zi-Jian; Zhu Long-Gen |
| 刊名 | CHINESE JOURNAL OF CHEMISTRY
 |
| 出版日期 | 2006-06-01 |
| 卷号 | 24期号:6页码:800-806 |
| 关键词 | Langmuir Monolayer Calixarene Condensed Domain Brewster Angle Microscopy |
| ISSN号 | 1001-604X |
| 英文摘要 | The Langmuir monolayer properties of lower rim aromatically substituted calix[4]arenes, 5,11,17,23-tetra-tert-butyl-25,27-bis(2-naphth-1'-ylacetylaminoethoxy)-26,28-dihydroxylcalix[4]arene (BNAEC), 5,11,17,23-tetra-tert-butyl-25,27-bis(2-benzoylamino ethoxy)-26,28-dihydroxylcalix[4]arene (BBAEC) and 5,11,17,23-tetra-tert-butyl-25,27-bis(2-cinnaminoylaminoethoxy)-26,28-dihydroxylcalix[4]arene (BCAEC), have been studied. Film balance measurements and Brewster angle microscopy (BAM) observation demonstrate that all the compounds can form Langmuir monolayers with different molecular limiting areas. BNAEC or BBAEC monolayer is able to form condensed domains during compression, while BCAEC monolayer can never form condensed domain. BNAEC monolayer is more readily to form condensed domain than BBAEC monolayer. Moreover, BNAEC monolayer can form the total condensed phase during compression even when T = 28 degrees C, while BBAEC monolayer can not when T >10 degrees C. The results imply that different lower rim aromatic substitutions affect essentially the intermolecular interaction and molecular packing in the monolayer at air/water interface. |
| 语种 | 英语 |
| WOS记录号 | WOS:000238343100016 |
| 出版者 | WILEY-V C H VERLAG GMBH |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/59369]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | He Wei-Jiang |
| 作者单位 | 1.Nanjing Univ, State Key Lab Coordinat Chem, Nanjing 210093, Jiangsu, Peoples R China 2.Chinese Acad Sci, Inst Chem, Ctr Mol Sci, Int Joint Lab, Beijing 100080, Peoples R China 3.Huaiyin Teachers Coll, Jiangsu Key lab chem Low Dimens Mat, Huaian 223300, Jiangsu, Peoples R China |
| 推荐引用方式 GB/T 7714 | He Wei-Jiang,Qiu Lin,Li Jun-Bai,et al. Structural effects on the Langmuir monolayers of calix[4]arene induced by lower rim aromatic substitution[J]. CHINESE JOURNAL OF CHEMISTRY,2006,24(6):800-806. |
| APA | He Wei-Jiang,Qiu Lin,Li Jun-Bai,Zhang Yu,Guo Zi-Jian,&Zhu Long-Gen.(2006).Structural effects on the Langmuir monolayers of calix[4]arene induced by lower rim aromatic substitution.CHINESE JOURNAL OF CHEMISTRY,24(6),800-806. |
| MLA | He Wei-Jiang,et al."Structural effects on the Langmuir monolayers of calix[4]arene induced by lower rim aromatic substitution".CHINESE JOURNAL OF CHEMISTRY 24.6(2006):800-806. |
入库方式： OAI收割
来源：化学研究所
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