Crystal structure and morphology of phenyl-capped tetraaniline in the leucoemeraldine oxidation state
文献类型:期刊论文
作者 | Zhou, YC; Geng, JX; Li, G; Zhou, EL; Chen, L; Zhang, WJ |
刊名 | JOURNAL OF POLYMER SCIENCE PART B-POLYMER PHYSICS
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出版日期 | 2006-02-15 |
卷号 | 44期号:4页码:764-769 |
关键词 | Crystal Structure Morphology Oligoaniline Tem |
ISSN号 | 0887-6266 |
DOI | 10.1002/polb.20700 |
英文摘要 | A series of crystals of phenyl-capped tetraaniline in the leucoemeraldine oxidation state were obtained at different isothermal temperatures and were observed directly under transmission electron microscope. The crystals obtained at higher temperatures exhibit more perfect structures than those obtained at lower temperatures. Both the lamella thickness and the crystal size increase with crystallization temperature. The tetraaniline is apt to form larger scale crystals under lower degree of supercooling. However, their crystal structures keep steady with the crystallization temperature. The tetramer was found to adopt a monoclinic lattice with unit cell parameter of a = 13.93 angstrom, b = 8.82 angstrom, c = 23.20 angstrom, and beta = 95.03 degrees, as determined using electron diffraction tilting method combined with wide-angle X-ray diffraction experiment. (c) 2006 Wiley Periodicals, Inc. |
语种 | 英语 |
WOS记录号 | WOS:000235088700014 |
出版者 | JOHN WILEY & SONS INC |
源URL | [http://ir.iccas.ac.cn/handle/121111/59421] ![]() |
专题 | 中国科学院化学研究所 |
通讯作者 | Zhou, YC |
作者单位 | 1.Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Polymer Phys & Chem, Grad Sch, Changchun 130022, Peoples R China 2.Beijing Univ Chem Technol, Sch Mat Sci & Engn, Beijing 100029, Peoples R China 3.Jilin Univ, AG Macdiarmid Lab, Changchun 130022, Peoples R China |
推荐引用方式 GB/T 7714 | Zhou, YC,Geng, JX,Li, G,et al. Crystal structure and morphology of phenyl-capped tetraaniline in the leucoemeraldine oxidation state[J]. JOURNAL OF POLYMER SCIENCE PART B-POLYMER PHYSICS,2006,44(4):764-769. |
APA | Zhou, YC,Geng, JX,Li, G,Zhou, EL,Chen, L,&Zhang, WJ.(2006).Crystal structure and morphology of phenyl-capped tetraaniline in the leucoemeraldine oxidation state.JOURNAL OF POLYMER SCIENCE PART B-POLYMER PHYSICS,44(4),764-769. |
MLA | Zhou, YC,et al."Crystal structure and morphology of phenyl-capped tetraaniline in the leucoemeraldine oxidation state".JOURNAL OF POLYMER SCIENCE PART B-POLYMER PHYSICS 44.4(2006):764-769. |
入库方式: OAI收割
来源:化学研究所
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