Structure characterization of melt drawn polyethylene ultrathin films
文献类型：期刊论文
| 作者 | Yan Chao; Zhang Jianming; Shen Deyan; Yan Shouke |
| 刊名 | CHINESE SCIENCE BULLETIN
 |
| 出版日期 | 2006-12-01 |
| 卷号 | 51期号:23页码:2844-2850 |
| 关键词 | Ultrathin Pe Film Orientation Infrared Spectroscopy Electron Microscopy |
| ISSN号 | 1001-6538 |
| DOI | 10.1007/s11434-006-2166-1 |
| 英文摘要 | Highly oriented ultrathin polyethylene (PE) films were prepared by a melt-draw technique. Transmission electron microscopy study on the obtained ultrathin films indicates that the melt drawn PE thin films consist of highly oriented edge-on lamellae aligned perpendicular to the drawing direction. Electron diffraction confirms that the PE chains in crystalline phase are highly oriented in film plane along the drawing direction, while only a random orientation of the crystallographic a- and b-axes can be described through electron diffraction. The IR results on the melt-drawn ultrathin PE films demonstrate that the PE molecular chains in both crystalline and amorphous phases of the melt drawn thin films are well oriented along the drawing direction. Moreover, the IR results indicate that in the crystalline phase, the crystallographic b-axis tend to lie in the thin film plane, while in the amorphous phase, the skeleton plane of some local chains prefers to parallel the film plane. The alignment of b-axis of PE crystals in ultrathin films originates from the fact that the b-axis is the fastest growth direction of the PE crystals. |
| 语种 | 英语 |
| WOS记录号 | WOS:000244136400006 |
| 出版者 | SCIENCE CHINA PRESS |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/59433]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Yan Shouke |
| 作者单位 | Chinese Acad Sci, Inst Chem, State Key Lab Polymer Phys & Chem, Beijing 100080, Peoples R China |
| 推荐引用方式 GB/T 7714 | Yan Chao,Zhang Jianming,Shen Deyan,et al. Structure characterization of melt drawn polyethylene ultrathin films[J]. CHINESE SCIENCE BULLETIN,2006,51(23):2844-2850. |
| APA | Yan Chao,Zhang Jianming,Shen Deyan,&Yan Shouke.(2006).Structure characterization of melt drawn polyethylene ultrathin films.CHINESE SCIENCE BULLETIN,51(23),2844-2850. |
| MLA | Yan Chao,et al."Structure characterization of melt drawn polyethylene ultrathin films".CHINESE SCIENCE BULLETIN 51.23(2006):2844-2850. |
入库方式： OAI收割
来源：化学研究所
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