Synthesis and characterization of porphyrin-ferrocene-fullerene triads
文献类型:期刊论文
作者 | Li, YJ; Gan, ZH; Wang, N; He, XR; Li, YL; Wang, S; Liu, HB; Araki, Y; Ito, O; Zhu, DB |
刊名 | TETRAHEDRON
![]() |
出版日期 | 2006-05-01 |
卷号 | 62期号:18页码:4285-4293 |
关键词 | Porphyrin Ferrocene Fullerene Conformation |
ISSN号 | 0040-4020 |
DOI | 10.1016/j.tet.2006.02.076 |
英文摘要 | Novel porphyrin-fullerene systems linked by ferrocene and related model compounds were successfully synthesized and characterized. Conforniationally flexible 1,1'-disubstituted ferrocene functioned as effective modulator of the conformation between porphyrin and fullerene, as H-1 NMR spectra indicated, the porphyrin and C-60 moieties in the triads showed gauche type conformation. The electrochemical and photophysical studies showed that there were considerable interactions between porphyrin and fullerene in the ground state due to intramolecular pi-stacking of the these two chromophores, assisted by the ferrocence linker. Fluorescence lifetime measurements indicated there might be two different quenching processes occurring simultaneously (intersystem crossing and electron transfer). (c) 2006 Elsevier Ltd. All rights reserved. |
语种 | 英语 |
WOS记录号 | WOS:000237126200001 |
出版者 | PERGAMON-ELSEVIER SCIENCE LTD |
源URL | [http://ir.iccas.ac.cn/handle/121111/59513] ![]() |
专题 | 中国科学院化学研究所 |
通讯作者 | Li, YL |
作者单位 | 1.Tohoku Univ, Inst Multidisciplinary Res Adv Mat, Aoba Ku, Sendai, Miyagi 9808577, Japan 2.Chinese Acad Sci, Grad Sch, Inst Chem, Key Lab Organ Solids, Beijing 100080, Peoples R China |
推荐引用方式 GB/T 7714 | Li, YJ,Gan, ZH,Wang, N,et al. Synthesis and characterization of porphyrin-ferrocene-fullerene triads[J]. TETRAHEDRON,2006,62(18):4285-4293. |
APA | Li, YJ.,Gan, ZH.,Wang, N.,He, XR.,Li, YL.,...&Zhu, DB.(2006).Synthesis and characterization of porphyrin-ferrocene-fullerene triads.TETRAHEDRON,62(18),4285-4293. |
MLA | Li, YJ,et al."Synthesis and characterization of porphyrin-ferrocene-fullerene triads".TETRAHEDRON 62.18(2006):4285-4293. |
入库方式: OAI收割
来源:化学研究所
浏览0
下载0
收藏0
其他版本
除非特别说明,本系统中所有内容都受版权保护,并保留所有权利。