A series of borate-rich metalloborophosphates Na-2[(MB3P2O11)-B-II(OH)]center dot 0.67H(2)O (M-II = Mg, Mn, Fe, Co, Ni, Cu, Zn): Synthesis, structure and magnetic susceptibility
文献类型：期刊论文
| 作者 | Yang, Tao; Li, Guobao; Ju, Jing; Liao, Fuhui; Xiong, Ming; Lin, Jianhua |
| 刊名 | JOURNAL OF SOLID STATE CHEMISTRY
 |
| 出版日期 | 2006-08-01 |
| 卷号 | 179期号:8页码:2534-2540 |
| 关键词 | Borophosphate Hydrothermal Structure Magnetic Open Framework |
| ISSN号 | 0022-4596 |
| DOI | 10.1016/j.jssc.2006.04.052 |
| 英文摘要 | A series of metalloborophosphates Na-2[(MB3P2O11)-B-II(OH)] center dot 0.67H(2)O (M-II = Mg, Mn, Fe, Co, Ni, Cu, Zn) have been prepared hydrothermally and their structures have been solved by single-crystal diffraction techniques. They all crystallize in a hexagonal space group P6(3) and form a 3D microporous structure with 12-membered ring channels consisted of octahedral ((MO6)-O-II), tetrahedral (BO4, PO4) and triangular (BO2(OH)) units, in which the counter Na+ cations and water molecules are located. The Na+ cations are mobile and can be exchanged by Li+ in a melt of LiNO3. Their open frameworks are thermal stable up to about 500 degrees C. Completed solid solutions between two different transition metals can also be obtained. Magnetic properties of Na-2[(MB3P2O11)-B-II(OH)]center dot 0.67H(2)O (M-II = Mn, Co, Ni, Cu) have been investigated. (c) 2006 Elsevier Inc. All rights reserved. |
| 语种 | 英语 |
| WOS记录号 | WOS:000239639600035 |
| 出版者 | ACADEMIC PRESS INC ELSEVIER SCIENCE |
| 源URL | [http://ir.iccas.ac.cn/handle/121111/59531]  |
| 专题 | 中国科学院化学研究所 |
| 通讯作者 | Lin, Jianhua |
| 作者单位 | 1.Peking Univ, Coll Chem & Mol Engn, State Key Lab Rare Earth Mat Chem & Applicat, Beijing Natl Lab Mol Sci, Beijing 100871, Peoples R China 2.Tohoku Univ, Grad Sch Sci, Dept Phys, Sendai, Miyagi 9808578, Japan 3.China Univ Geosci, Xray Lab, Beijing 100083, Peoples R China |
| 推荐引用方式 GB/T 7714 | Yang, Tao,Li, Guobao,Ju, Jing,et al. A series of borate-rich metalloborophosphates Na-2[(MB3P2O11)-B-II(OH)]center dot 0.67H(2)O (M-II = Mg, Mn, Fe, Co, Ni, Cu, Zn): Synthesis, structure and magnetic susceptibility[J]. JOURNAL OF SOLID STATE CHEMISTRY,2006,179(8):2534-2540. |
| APA | Yang, Tao,Li, Guobao,Ju, Jing,Liao, Fuhui,Xiong, Ming,&Lin, Jianhua.(2006).A series of borate-rich metalloborophosphates Na-2[(MB3P2O11)-B-II(OH)]center dot 0.67H(2)O (M-II = Mg, Mn, Fe, Co, Ni, Cu, Zn): Synthesis, structure and magnetic susceptibility.JOURNAL OF SOLID STATE CHEMISTRY,179(8),2534-2540. |
| MLA | Yang, Tao,et al."A series of borate-rich metalloborophosphates Na-2[(MB3P2O11)-B-II(OH)]center dot 0.67H(2)O (M-II = Mg, Mn, Fe, Co, Ni, Cu, Zn): Synthesis, structure and magnetic susceptibility".JOURNAL OF SOLID STATE CHEMISTRY 179.8(2006):2534-2540. |
入库方式： OAI收割
来源：化学研究所
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